(Z)-7-<4-<(tert-Butyldimethylsilyl)oxy>-3,5-dimethylphenyl>-1-phenyl-1-heptene

Base Information

Chemical Name:(Z)-7-<4-<(tert-Butyldimethylsilyl)oxy>-3,5-dimethylphenyl>-1-phenyl-1-heptene
CAS No.:149777-37-7
Molecular Formula:C₂₇H₄₀OSi
Molecular Weight:408.7
Hs Code.:

Synonyms:(Z)-7-<4-<(tert-Butyldimethylsilyl)oxy>-3,5-dimethylphenyl>-1-phenyl-1-heptene

Suppliers and Price of (Z)-7-<4-<(tert-Butyldimethylsilyl)oxy>-3,5-dimethylphenyl>-1-phenyl-1-heptene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (Z)-7-<4-<(tert-Butyldimethylsilyl)oxy>-3,5-dimethylphenyl>-1-phenyl-1-heptene

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Technology Process of (Z)-7-<4-<(tert-Butyldimethylsilyl)oxy>-3,5-dimethylphenyl>-1-phenyl-1-heptene

There total 4 articles about (Z)-7-<4-<(tert-Butyldimethylsilyl)oxy>-3,5-dimethylphenyl>-1-phenyl-1-heptene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 144180-70-1
6-<4-<(tert-butyldimethylsilyl)oxy>-3,5-dimethylphenyl>hexanol

: 149777-37-7
(Z)-7-<4-<(tert-Butyldimethylsilyl)oxy>-3,5-dimethylphenyl>-1-phenyl-1-heptene

Guidance literature:: Multi-step reaction with 4 steps

1: 92 percent / Ph₃P, CBr₄ / diethyl ether / 2.5 h / Ambient temperature

2: 90 percent / NaI / acetone / 3 h / Heating

3: 96 percent / 20 h / 70 °C

4: 1.) KN(TMS)2, HMPA / 1.) THF, room temp., 20 min; -78 deg C, 10 min, 2.) -78 deg C to room temp., 1 h; room temp., 1 h

With N,N,N,N,N,N-hexamethylphosphoric triamide; carbon tetrabromide; potassium hexamethylsilazane; triphenylphosphine; sodium iodide; In diethyl ether; acetone;
DOI:10.1021/jo00071a024

Reference yield:

: 149777-35-5
1-<(tert-Butyldimethylsilyl)oxy>-4-(6-bromohexyl)-2,6-dimethylbenzene

: 149777-37-7
(Z)-7-<4-<(tert-Butyldimethylsilyl)oxy>-3,5-dimethylphenyl>-1-phenyl-1-heptene

Guidance literature:: Multi-step reaction with 3 steps

1: 90 percent / NaI / acetone / 3 h / Heating

2: 96 percent / 20 h / 70 °C

3: 1.) KN(TMS)2, HMPA / 1.) THF, room temp., 20 min; -78 deg C, 10 min, 2.) -78 deg C to room temp., 1 h; room temp., 1 h

With N,N,N,N,N,N-hexamethylphosphoric triamide; potassium hexamethylsilazane; sodium iodide; In acetone;
DOI:10.1021/jo00071a024

Reference yield:

: 149777-36-6
1-<(tert-Butyldimethylsilyl)oxy>-4-(6-iodohexyl)-2,6-dimethylbenzene

: 149777-37-7
(Z)-7-<4-<(tert-Butyldimethylsilyl)oxy>-3,5-dimethylphenyl>-1-phenyl-1-heptene

Guidance literature:: Multi-step reaction with 2 steps

1: 96 percent / 20 h / 70 °C

2: 1.) KN(TMS)2, HMPA / 1.) THF, room temp., 20 min; -78 deg C, 10 min, 2.) -78 deg C to room temp., 1 h; room temp., 1 h

With N,N,N,N,N,N-hexamethylphosphoric triamide; potassium hexamethylsilazane;
DOI:10.1021/jo00071a024