Chlorozinc(1+);1-methanidyl-3-methylbenzene

Base Information

Chemical Name:Chlorozinc(1+);1-methanidyl-3-methylbenzene
CAS No.:312693-20-2
Molecular Formula:C₈H₉ClZn
Molecular Weight:206.002
Hs Code.:
DSSTox Substance ID:DTXSID50409302
Mol file:312693-20-2.mol

Synonyms:chlorozinc(1+);1-methanidyl-3-methylbenzene;DTXSID50409302;J-018343

Suppliers and Price of Chlorozinc(1+);1-methanidyl-3-methylbenzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
3-Methylbenzylzinc chloride solution 0.5M in THF
50ml
$ 203.00

Rieke Metals
3-Methylbenzylzincchloride
100mL
$ 482.00

Rieke Metals
3-Methylbenzylzincchloride
50mL
$ 263.00

American Custom Chemicals Corporation
3-METHYLBENZYLZINC CHLORIDE 95.00%
1L
$ 7969.50

American Custom Chemicals Corporation
3-METHYLBENZYLZINC CHLORIDE 95.00%
500ML
$ 5370.75

American Custom Chemicals Corporation
3-METHYLBENZYLZINC CHLORIDE 95.00%
100ML
$ 2818.20

Total 6 raw suppliers

Chemical Property of Chlorozinc(1+);1-methanidyl-3-methylbenzene

Chemical Property:

Boiling Point:°Cat760mmHg
Flash Point:°C
PSA：0.00000
Density:g/cm³
LogP:2.99770
Storage Temp.:2-8°C
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:203.968420
Heavy Atom Count:10
Complexity:68.4

Purity/Quality:

99% ^*data from raw suppliers

3-Methylbenzylzinc chloride solution 0.5M in THF ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:F,Xn
Statements: 14-19-22-36/38-40-36/37-11
Safety Statements: 16-26-33-36-36/37

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC(=CC=C1)[CH2-].Cl[Zn+]

Technology Process of Chlorozinc(1+);1-methanidyl-3-methylbenzene

There total 1 articles about Chlorozinc(1+);1-methanidyl-3-methylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 620-19-9
1-chloromethyl-3-methyl-benzene

: 7646-85-7,24359-56-6
zinc(II) chloride

: 312693-20-2
(3-methylbenzyl)zinc(II) chloride

Guidance literature:: 1-chloromethyl-3-methyl-benzene; In tetrahydrofuran; at -78 ℃; for 1h;

zinc(II) chloride; In tetrahydrofuran; at 25 ℃; for 1h; Inert atmosphere;
DOI:10.1002/anie.202109290

Reference yield: 51.0%

: 312693-20-2
(3-methylbenzyl)zinc(II) chloride

: C₁₆H₂₀F₂O₃S

: C₂₄H₂₉FO₃S

Guidance literature:: With [RhCl((S,S)-Fc-tfb(*))]2; zinc(II) chloride; In tetrahydrofuran; at 25 ℃; for 14h; enantioselective reaction; Schlenk technique; Inert atmosphere;
DOI:10.1002/anie.202109290