N₁,N₃-bis(4-tert-butylphenyl)-N₁,N₃-bis(naphthalen-1-yl)-5-(thiophen-2-yl)benzene-1,3-diamine

Base Information

• Chemical Name: N₁,N₃-bis(4-tert-butylphenyl)-N₁,N₃-bis(naphthalen-1-yl)-5-(thiophen-2-yl)benzene-1,3-diamine
• CAS No.: 1119083-63-4
• Molecular Formula: C₅₀H₄₆N₂S
• Molecular Weight: 706.995
• Mol file: 1119083-63-4.mol

Synonyms:N₁,N₃-bis(4-tert-butylphenyl)-N₁,N₃-bis(naphthalen-1-yl)-5-(thiophen-2-yl)benzene-1,3-diamine

Chemical Property of N₁,N₃-bis(4-tert-butylphenyl)-N₁,N₃-bis(naphthalen-1-yl)-5-(thiophen-2-yl)benzene-1,3-diamine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N₁,N₃-bis(4-tert-butylphenyl)-N₁,N₃-bis(naphthalen-1-yl)-5-(thiophen-2-yl)benzene-1,3-diamine

There total 1 articles about N₁,N₃-bis(4-tert-butylphenyl)-N₁,N₃-bis(naphthalen-1-yl)-5-(thiophen-2-yl)benzene-1,3-diamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

1,3-dibromo-5-(2'-thienyl)benzene (145493-76-1) + N-(4-(tert-butyl)phenyl)naphthalen-1-amine (4572-48-9) → N1,N3-bis(4-tert-butylphenyl)-N1,N3-bis(naphthalen-1-yl)-5-(thiophen-2-yl)benzene-1,3-diamine (1119083-63-4)

Guidance literature:

With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium⁽⁰⁾; sodium t-butanolate; In toluene; at 80 ℃; Inert atmosphere;

DOI:10.1002/chem.200801694

Reference yield: 72.0%

4,7-dibromobenzo[c][1,2,5]thiadiazole (15155-41-6) + N1,N3-bis(4-tert-butylphenyl)-N1,N3-bis(naphthalen-1-yl)-5-(thiophen-2-yl)benzene-1,3-diamine (1119083-63-4) → 5-{5-[4-(5-{3,5-bis[N-(4-tert-butylphenyl)-N-(naphthalen-1-yl)amino]phenyl}thiophen-2-yl)benzo[c][1,2,5]thiadiazol-7-yl]thiophen-2-yl}-N1,N3-bis(4-tert-butylphenyl)-N1,N3-bis(naphthalen-1-yl)benzene-1,3-diamine (1119083-67-8)

Guidance literature:

N₁,N₃-bis(4-tert-butylphenyl)-N₁,N₃-bis(naphthalen-1-yl)-5-(thiophen-2-yl)benzene-1,3-diamine; With n-butyllithium; In tetrahydrofuran; hexane; at -75 - 0 ℃; Inert atmosphere;

With tributyltin chloride; In tetrahydrofuran; hexane; at -75 - 20 ℃; Inert atmosphere;

4,7-dibromobenzo[c][1,2,5]thiadiazole; With bis-triphenylphosphine-palladium(II) chloride; In N,N-dimethyl-formamide; at 80 ℃; for 18h; Inert atmosphere;

DOI:10.1002/chem.200801694

upstream raw materials:

1,3-dibromo-5-(2'-thienyl)benzene

N-(4-(tert-butyl)phenyl)naphthalen-1-amine

Downstream raw materials:

5-{5-[4-(5-{3,5-bis[N-(4-tert-butylphenyl)-N-(naphthalen-1-yl)amino]phenyl}thiophen-2-yl)benzo[c][1,2,5]thiadiazol-7-yl]thiophen-2-yl}-N₁,N₃-bis(4-tert-butylphenyl)-N₁,N₃-bis(naphthalen-1-yl)benzene-1,3-diamine