(Z)-2-(2-(2-methylphenyl)vinyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Base Information

Chemical Name:(Z)-2-(2-(2-methylphenyl)vinyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
CAS No.:1361046-87-8
Molecular Formula:C₁₅H₂₁BO₂
Molecular Weight:244.142
Hs Code.:

Synonyms:(Z)-2-(2-(2-methylphenyl)vinyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

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Chemical Property of (Z)-2-(2-(2-methylphenyl)vinyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

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Technology Process of (Z)-2-(2-(2-methylphenyl)vinyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

There total 4 articles about (Z)-2-(2-(2-methylphenyl)vinyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

: 615-37-2
ortho-methylphenyl iodide

: (Z)-2-(2-bromovinyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: 1361046-87-8
(Z)-2-(2-(2-methylphenyl)vinyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Guidance literature:: ortho-methylphenyl iodide; With tert.-butyl lithium; In tetrahydrofuran; pentane; at -78 ℃; Inert atmosphere; Schlenk technique;

With zinc(II) chloride; In tetrahydrofuran; diethyl ether; pentane; at -78 - 20 ℃; for 0.5h; Inert atmosphere; Schlenk technique;

(Z)-2-(2-bromovinyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane; With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; diethyl ether; pentane; at 20 ℃; for 2h; Inert atmosphere; Schlenk technique;
DOI:10.1021/acs.joc.0c00341

Reference yield:

: 766-47-2
1-ethynyl-2-methylbenzene

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

: 1294009-26-9
4,4,5,5-tetramethyl-2-[(E)-2-(o-tolyl)vinyl]-1,3,2-dioxaborolane

: 1361046-87-8
(Z)-2-(2-(2-methylphenyl)vinyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Guidance literature:: With chloro(1,5-cyclooctadiene)rhodium(I) dimer; triethylamine; tricyclohexylphosphine; In tetrahydrofuran; at 25 ℃; for 4h; regioselective reaction; Inert atmosphere;
DOI:10.1002/chem.201102729

Reference yield:

: 766-47-2
1-ethynyl-2-methylbenzene

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

: 1361046-87-8
(Z)-2-(2-(2-methylphenyl)vinyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Guidance literature:: With C₃₁H₅₂FeN₄P₂; In tetrahydrofuran; at 23 - 28 ℃; for 4h; diastereoselective reaction; Glovebox; Sealed tube; Inert atmosphere;
DOI:10.1021/acs.inorgchem.0c02057