(1S,2S,4S)-4-Hydroxy-1-methyl-cyclohexane-1,2-dicarboxylic acid 1-methyl ester

Base Information

Chemical Name:(1S,2S,4S)-4-Hydroxy-1-methyl-cyclohexane-1,2-dicarboxylic acid 1-methyl ester
CAS No.:74320-49-3
Molecular Formula:C₁₀H₁₆O₅
Molecular Weight:216.234
Hs Code.:

Synonyms:(1S,2S,4S)-4-Hydroxy-1-methyl-cyclohexane-1,2-dicarboxylic acid 1-methyl ester

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1S,2S,4S)-4-Hydroxy-1-methyl-cyclohexane-1,2-dicarboxylic acid 1-methyl ester

Chemical Property:

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Technology Process of (1S,2S,4S)-4-Hydroxy-1-methyl-cyclohexane-1,2-dicarboxylic acid 1-methyl ester

There total 4 articles about (1S,2S,4S)-4-Hydroxy-1-methyl-cyclohexane-1,2-dicarboxylic acid 1-methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 74320-47-1,74320-48-2
(1S,2S,5S)-2-Methyl-7-oxo-6-oxa-bicyclo[3.2.1]octane-2-carboxylic acid methyl ester

: 74320-49-3
(1S,2S,4S)-4-Hydroxy-1-methyl-cyclohexane-1,2-dicarboxylic acid 1-methyl ester

Guidance literature:: With potassium hydroxide; In methanol;
DOI:10.3987/R-1987-05-1203

Reference yield:

: 93603-11-3
1-methyl hydrogen 1,2-cis-1,2-cyclohex-4-ene dicarboxylate

: 74320-49-3
(1S,2S,4S)-4-Hydroxy-1-methyl-cyclohexane-1,2-dicarboxylic acid 1-methyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 70 percent / I₂, KI, aq. Na₂CO₃

2: 97 percent / tri-n-butyltinhydride / diethyl ether / 1.5 h

3: LDA / tetrahydrofuran / 20 h / Ambient temperature

4: 10percent KOH / methanol

With potassium hydroxide; iodine; tri-n-butyl-tin hydride; sodium carbonate; potassium iodide; lithium diisopropyl amide; In tetrahydrofuran; methanol; diethyl ether;
DOI:10.3987/R-1987-05-1203

Reference yield:

: 7771-14-4,19903-11-8,74320-46-0,78176-49-5,188796-05-6
(1S,2R,5S)-7-Oxo-6-oxa-bicyclo[3.2.1]octane-2-carboxylic acid methyl ester

: 74320-49-3
(1S,2S,4S)-4-Hydroxy-1-methyl-cyclohexane-1,2-dicarboxylic acid 1-methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: LDA / tetrahydrofuran / 20 h / Ambient temperature

2: 10percent KOH / methanol

With potassium hydroxide; lithium diisopropyl amide; In tetrahydrofuran; methanol;
DOI:10.3987/R-1987-05-1203