11-benzyloxy-2-dodecene-1,4-diol

Base Information

Chemical Name:11-benzyloxy-2-dodecene-1,4-diol
CAS No.:370863-10-8
Molecular Formula:C₁₉H₃₀O₃
Molecular Weight:306.445
Hs Code.:

Synonyms:11-benzyloxy-2-dodecene-1,4-diol

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Chemical Property of 11-benzyloxy-2-dodecene-1,4-diol

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Technology Process of 11-benzyloxy-2-dodecene-1,4-diol

There total 8 articles about 11-benzyloxy-2-dodecene-1,4-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 370863-09-5
11-benzyloxy-1-(tetrahydro-2H-pyran-2-yl)-oxy-2-dodecen-4-ol

: 370863-10-8
11-benzyloxy-2-dodecene-1,4-diol

Guidance literature:: With tin(ll) chloride; In methanol; at 20 ℃; for 6h;

Reference yield:

: 13379-30-1
8-(tetrahydro-2H-pyran-2-yl)oxy-2-octanol

: 370863-10-8
11-benzyloxy-2-dodecene-1,4-diol

Guidance literature:: Multi-step reaction with 5 steps

1.1: NaH; tetra-n-butylammonium chloride / dimethylformamide / 0.5 h / 0 °C

1.2: 84 percent / dimethylformamide / 4 h

2.1: 89 percent / stannous chloride / methanol / 20 °C

3.1: 89 percent / Ph₃P; imidazole; I₂ / diethyl ether / 0 °C

4.1: t-BuLi / diethyl ether; pentane / 1 h / -78 °C

4.2: 51 percent / diethyl ether; pentane / -78 - 20 °C

5.1: 88 percent / stannous chloride / methanol / 6 h / 20 °C

With 1H-imidazole; tetrabutyl-ammonium chloride; iodine; tert.-butyl lithium; sodium hydride; triphenylphosphine; tin(ll) chloride; In methanol; diethyl ether; N,N-dimethyl-formamide; pentane;

Reference yield:

: 629-30-1
1,7-heptandiol

: 370863-10-8
11-benzyloxy-2-dodecene-1,4-diol

Guidance literature:: Multi-step reaction with 8 steps

1.1: 75.53 percent / stannous chloride dihydrate / CHCl₃ / 24 h

2.1: 60.57 percent / CrO₃*pyridine / CHCl₃ / 0 °C

3.1: Mg / diethyl ether

3.2: 93 percent / diethyl ether / 0.5 h

4.1: NaH; tetra-n-butylammonium chloride / dimethylformamide / 0.5 h / 0 °C

4.2: 84 percent / dimethylformamide / 4 h

5.1: 89 percent / stannous chloride / methanol / 20 °C

6.1: 89 percent / Ph₃P; imidazole; I₂ / diethyl ether / 0 °C

7.1: t-BuLi / diethyl ether; pentane / 1 h / -78 °C

7.2: 51 percent / diethyl ether; pentane / -78 - 20 °C

8.1: 88 percent / stannous chloride / methanol / 6 h / 20 °C

With 1H-imidazole; chromium trioxide-pyridine complex; tetrabutyl-ammonium chloride; iodine; tert.-butyl lithium; sodium hydride; magnesium; triphenylphosphine; tin(ll) chloride; In methanol; diethyl ether; chloroform; N,N-dimethyl-formamide; pentane; 3.1: Grignard reaction / 3.2: Grignard reaction;