(3S,6S)-2-benzyloxycarbonyl-6-<<(tert-butyldimethylsilyl)oxy>methyl>perhydro-1,2-oxazine-3,6-dicarboxylic acid

Base Information

Chemical Name:(3S*,6S*)-2-benzyloxycarbonyl-6-<<(tert-butyldimethylsilyl)oxy>methyl>perhydro-1,2-oxazine-3,6-dicarboxylic acid
CAS No.:108634-81-7
Molecular Formula:C₂₁H₃₁NO₈Si
Molecular Weight:453.565
Hs Code.:

Synonyms:(3S*,6S*)-2-benzyloxycarbonyl-6-<<(tert-butyldimethylsilyl)oxy>methyl>perhydro-1,2-oxazine-3,6-dicarboxylic acid

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Chemical Property of (3S*,6S*)-2-benzyloxycarbonyl-6-<<(tert-butyldimethylsilyl)oxy>methyl>perhydro-1,2-oxazine-3,6-dicarboxylic acid

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Technology Process of (3S*,6S*)-2-benzyloxycarbonyl-6-<<(tert-butyldimethylsilyl)oxy>methyl>perhydro-1,2-oxazine-3,6-dicarboxylic acid

There total 1 articles about (3S*,6S*)-2-benzyloxycarbonyl-6-<<(tert-butyldimethylsilyl)oxy>methyl>perhydro-1,2-oxazine-3,6-dicarboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 108634-78-2
3-benzyloxycarbonyl-1-<<(tert-butyldimethylsilyl)oxy>methyl>-2-oxa-3-azabicyclo<2.2.2>oct-5-ene

: 108634-81-7
(3S*,6S*)-2-benzyloxycarbonyl-6-<<(tert-butyldimethylsilyl)oxy>methyl>perhydro-1,2-oxazine-3,6-dicarboxylic acid

Guidance literature:: With potassium permanganate; tetra(n-butyl)ammonium hydrogensulfate; In water; benzene; Ambient temperature;
DOI:10.1016/S0040-4020(01)87377-4

Reference yield:

: 108634-81-7
(3S*,6S*)-2-benzyloxycarbonyl-6-<<(tert-butyldimethylsilyl)oxy>methyl>perhydro-1,2-oxazine-3,6-dicarboxylic acid

: 108634-83-9
(3S*,6S*)-2-benzyloxycarbonyl-6-hydroxymethylperhydro-1,2-oxazine-3,6-dicarboxylic acid

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; for 2h; Yield given; Ambient temperature;
DOI:10.1016/S0040-4020(01)87377-4

Reference yield:

: 108634-81-7
(3S*,6S*)-2-benzyloxycarbonyl-6-<<(tert-butyldimethylsilyl)oxy>methyl>perhydro-1,2-oxazine-3,6-dicarboxylic acid

: 108659-39-8
benzyl (4S*,7S*)-6-benzyloxycarbonyl-1-oxo-2,5-dioxa-6-azaspiro<3.5>nonane-7-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: n-Bu₄NF / tetrahydrofuran / 2 h / Ambient temperature

2: 39 percent / pyridine / CH₂Cl₂ / Ambient temperature

With pyridine; tetrabutyl ammonium fluoride; In tetrahydrofuran; dichloromethane;
DOI:10.1016/S0040-4020(01)87377-4