phosphoric acid diallyl ester 3-(tert-butyl-dimethyl-silanyloxy)-1-{3-[3-(tert-butyl-dimethyl-silanyloxy)-6-oxo-3,6-dihydro-2H-pyran-2-yl]-1-methyl-1-triethylsilanyloxy-allyl}-10-(tert-butyl-diphenyl-silanyloxy)-deca-4,6,8-trienyl ester

Base Information

Chemical Name:phosphoric acid diallyl ester 3-(tert-butyl-dimethyl-silanyloxy)-1-{3-[3-(tert-butyl-dimethyl-silanyloxy)-6-oxo-3,6-dihydro-2H-pyran-2-yl]-1-methyl-1-triethylsilanyloxy-allyl}-10-(tert-butyl-diphenyl-silanyloxy)-deca-4,6,8-trienyl ester
CAS No.:915700-44-6
Molecular Formula:C₅₉H₉₅O₁₀PSi₄
Molecular Weight:1107.71
Hs Code.:

phosphoric acid diallyl ester 3-(<i>tert</i>-butyl-dimethyl-silanyloxy)-1-{3-[3-(<i>tert</i>-butyl-dimethyl-silanyloxy)-6-oxo-3,6-dihydro-2<i>H</i>-pyran-2-yl]-1-methyl-1-triethylsilanyloxy-allyl}-10-(<i>tert</i>-butyl-diphenyl-silanyloxy)-deca-4,6,8-trienyl ester

Synonyms:phosphoric acid diallyl ester 3-(tert-butyl-dimethyl-silanyloxy)-1-{3-[3-(tert-butyl-dimethyl-silanyloxy)-6-oxo-3,6-dihydro-2H-pyran-2-yl]-1-methyl-1-triethylsilanyloxy-allyl}-10-(tert-butyl-diphenyl-silanyloxy)-deca-4,6,8-trienyl ester

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Chemical Property of phosphoric acid diallyl ester 3-(tert-butyl-dimethyl-silanyloxy)-1-{3-[3-(tert-butyl-dimethyl-silanyloxy)-6-oxo-3,6-dihydro-2H-pyran-2-yl]-1-methyl-1-triethylsilanyloxy-allyl}-10-(tert-butyl-diphenyl-silanyloxy)-deca-4,6,8-trienyl ester

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Technology Process of phosphoric acid diallyl ester 3-(tert-butyl-dimethyl-silanyloxy)-1-{3-[3-(tert-butyl-dimethyl-silanyloxy)-6-oxo-3,6-dihydro-2H-pyran-2-yl]-1-methyl-1-triethylsilanyloxy-allyl}-10-(tert-butyl-diphenyl-silanyloxy)-deca-4,6,8-trienyl ester

There total 4 articles about phosphoric acid diallyl ester 3-(tert-butyl-dimethyl-silanyloxy)-1-{3-[3-(tert-butyl-dimethyl-silanyloxy)-6-oxo-3,6-dihydro-2H-pyran-2-yl]-1-methyl-1-triethylsilanyloxy-allyl}-10-(tert-butyl-diphenyl-silanyloxy)-deca-4,6,8-trienyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: phosphorous acid diallyl ester 3-(tert-butyl-dimethyl-silanyloxy)-1-{3-[3-(tert-butyl-dimethyl-silanyloxy)-6-oxo-3,6-dihydro-2H-pyran-2-yl]-1-methyl-1-triethylsilanyloxy-allyl}-10-(tert-butyl-diphenyl-silanyloxy)-deca-4,6,8-trienyl ester

: 915700-44-6
phosphoric acid diallyl ester 3-(tert-butyl-dimethyl-silanyloxy)-1-{3-[3-(tert-butyl-dimethyl-silanyloxy)-6-oxo-3,6-dihydro-2H-pyran-2-yl]-1-methyl-1-triethylsilanyloxy-allyl}-10-(tert-butyl-diphenyl-silanyloxy)-deca-4,6,8-trienyl ester

Guidance literature:: With tert.-butylhydroperoxide; In methanol; dichloromethane; at 0 ℃; for 3.5h;
DOI:10.1021/ol062111u

Reference yield:

: 915700-43-5
(5S,6S)-5-(tert-Butyl-dimethyl-silanyloxy)-6-[(1E,7Z)-(3R,4R,6R)-6-(tert-butyl-dimethyl-silanyloxy)-4-hydroxy-8-iodo-3-methyl-3-triethylsilanyloxy-octa-1,7-dienyl]-5,6-dihydro-pyran-2-one

: 915700-44-6
phosphoric acid diallyl ester 3-(tert-butyl-dimethyl-silanyloxy)-1-{3-[3-(tert-butyl-dimethyl-silanyloxy)-6-oxo-3,6-dihydro-2H-pyran-2-yl]-1-methyl-1-triethylsilanyloxy-allyl}-10-(tert-butyl-diphenyl-silanyloxy)-deca-4,6,8-trienyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 96 percent / Pd(MeCN)2Cl₂ / dimethylformamide / 12 h / 0 °C

2: tetrazole / CH₂Cl₂ / 0.25 h / 20 °C

3: 99 mg / TBHP / CH₂Cl₂; methanol / 3.5 h / 0 °C

With 1H-tetrazole; tert.-butylhydroperoxide; dichloro bis(acetonitrile) palladium(II); In methanol; dichloromethane; N,N-dimethyl-formamide; 1: Stille coupling;
DOI:10.1021/ol062111u

Reference yield:

: (5S,6S,1'E,3'R,4'R,6'R,7'EZ)-5-(tert-butyl(dimethyl)silyloxy)-6-[6'-(tert-butyl(dimethyl)silyloxy)-8'-iodo-3'-methyl-3',4'-bis(triethylsilyloxy)-1',7'-octadienyl]-5,6-dihydro-2H-pyran-2-one

: 915700-44-6
phosphoric acid diallyl ester 3-(tert-butyl-dimethyl-silanyloxy)-1-{3-[3-(tert-butyl-dimethyl-silanyloxy)-6-oxo-3,6-dihydro-2H-pyran-2-yl]-1-methyl-1-triethylsilanyloxy-allyl}-10-(tert-butyl-diphenyl-silanyloxy)-deca-4,6,8-trienyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 37 percent / HCl / tetrahydrofuran; acetonitrile / 4 h / -10 °C

2: 96 percent / Pd(MeCN)2Cl₂ / dimethylformamide / 12 h / 0 °C

3: tetrazole / CH₂Cl₂ / 0.25 h / 20 °C

4: 99 mg / TBHP / CH₂Cl₂; methanol / 3.5 h / 0 °C

With 1H-tetrazole; hydrogenchloride; tert.-butylhydroperoxide; dichloro bis(acetonitrile) palladium(II); In tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide; acetonitrile; 2: Stille coupling;
DOI:10.1021/ol062111u