(5,10,15,20-tetraphenylporphyrin)-ethyl-scandium(III)

Base Information

• Chemical Name: (5,10,15,20-tetraphenylporphyrin)-ethyl-scandium(III)
• CAS No.: 1001207-13-1
• Molecular Formula: C₄₆H₃₃N₄Sc
• Molecular Weight: 686.751
• Mol file: 1001207-13-1.mol

Synonyms:(5,10,15,20-tetraphenylporphyrin)-ethyl-scandium(III)

Chemical Property of (5,10,15,20-tetraphenylporphyrin)-ethyl-scandium(III)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of (5,10,15,20-tetraphenylporphyrin)-ethyl-scandium(III)

There total 1 articles about (5,10,15,20-tetraphenylporphyrin)-ethyl-scandium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

(5,10,15,20-tetraphenylporphyrin)-chloro-scandium(III)*2,5(1-chloronaphthalene) + ethylmagnesium chloride (2386-64-3) → (5,10,15,20-tetraphenylporphyrin)-ethyl-scandium(III) (1001207-13-1)

Guidance literature:

With dioxane; In diethyl ether; under Ar; anhyd. dioxane added dropwise to soln. of EtMgCl in dry Et2O; stirred for 8 h; solvent removed under reduced pressure (Et2Mg); Sc compd. added to dry degassed toluene, degassed by freeze-thaw cycle; transferred to Et2Mg; stirred for 14 h; soln. filtered through sintered glass frit under Ar; solvent removed under reduced repssure;

DOI:10.1016/j.molstruc.2007.02.018

Reference yield:

(5,10,15,20-tetraphenylporphyrin)-ethyl-scandium(III) (1001207-13-1) → bis[(μ-hydroxo)-(5,10,15,20-tetraphenylporphyrin) scandium(III)]

Guidance literature:

With air; In diethyl ether; Sc complex in dry Et2O exposed to atmosphere for 3 h; monitored by UV-vis spectra;

DOI:10.1016/j.molstruc.2007.02.018

upstream raw materials:

ethylmagnesium chloride