3-FLUOROPHENANTHRENE

Base Information

• Chemical Name: 3-FLUOROPHENANTHRENE
• CAS No.: 440-40-4
• Molecular Formula: C14H9 F
• Molecular Weight: 196.224
• Hs Code.: 2903999090
• Mol file: 440-40-4.mol

Synonyms:3-Fluorophenanthrene

Chemical Property of 3-FLUOROPHENANTHRENE

Chemical Property:

• PSA: 0.00000
• LogP: 4.13210

Purity/Quality:

98%min ^*data from raw suppliers

3-FLUOROPHENANTHRENE 98.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-FLUOROPHENANTHRENE

There total 18 articles about 3-FLUOROPHENANTHRENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

1-fluoro-4-styrylbenzene (718-25-2,1657-46-1,17404-69-2) → 3-Fluorophenanthrene (440-40-4)

Guidance literature:

With iodine; In tetrahydrofuran; toluene; for 24h; Photolysis;

DOI:10.1016/j.tetlet.2012.11.022

Reference yield: 94.0%

5′-fluoro-2′-styryl-[1,1′-biphenyl]-2-carbaldehyde → 3-Fluorophenanthrene (440-40-4)

Guidance literature:

With phosphomolybdic acid; In 1,2-dichloro-ethane; at 25 ℃; for 12h; Sealed tube;

DOI:10.1021/acs.joc.1c02385

Reference yield: 82.0%

2-bromo-1-(4-fluorophenyl)ethylene (870122-74-0) + 2-(trimethylsilyl)phenyl trifluoromethanesulfonate (88284-48-4) → 3-Fluorophenanthrene (440-40-4)

Guidance literature:

With cesium fluoride; In acetonitrile; at 50 ℃; for 12h; Schlenk technique; Inert atmosphere;

DOI:10.1021/acs.joc.9b01644

upstream raw materials:

C₁₄H₁₀BrF

(E)-4-fluorostilbene

3-aminophenanthrene

N-(phenanthren-3-yl)acetamide

Refernces

• 1、 Singh, Vikram,Verma, Ram Subhawan,Khatana, Anil K.,Tiwari, Bhoopendra. "Construction of Phenanthrenes and Chrysenes from β-Bromovinylarenes via Aryne Diels-Alder Reaction/Aromatization". . p. 14161 - 14167. Retrieved 2019/10/28.
• 2、 Chen, Ming,Zhao, Xinxin,Yang, Chao,Wang, Yanpei,Xia, Wujiong. "Further insight into the photochemical behavior of 3-aryl-N-(arylsulfonyl)propiolamides: tunable synthetic route to phenanthrenes". . p. 12022 - 12026. Retrieved 2017/03/01.