(3EZ,8R,9R,10S,11S,12S)-7-hydroxy-9-(4-methoxyphenylmethoxy)-4,6,8,10,12-pentamethyl-11-(triethylsilyloxy)-13-[(1,1-dimethylethyl)diphenylsilyloxy]-3-[tris(1-methylethyl)silyloxy]-tridec-3-en-5-one

Base Information

Chemical Name:(3EZ,8R,9R,10S,11S,12S)-7-hydroxy-9-(4-methoxyphenylmethoxy)-4,6,8,10,12-pentamethyl-11-(triethylsilyloxy)-13-[(1,1-dimethylethyl)diphenylsilyloxy]-3-[tris(1-methylethyl)silyloxy]-tridec-3-en-5-one
CAS No.:1201668-18-9
Molecular Formula:C₅₇H₉₄O₇Si₃
Molecular Weight:975.626
Hs Code.:

(3EZ,8R,9R,10S,11S,12S)-7-hydroxy-9-(4-methoxyphenylmethoxy)-4,6,8,10,12-pentamethyl-11-(triethylsilyloxy)-13-[(1,1-dimethylethyl)diphenylsilyloxy]-3-[tris(1-methylethyl)silyloxy]-tridec-3-en-5-one

Synonyms:(3EZ,8R,9R,10S,11S,12S)-7-hydroxy-9-(4-methoxyphenylmethoxy)-4,6,8,10,12-pentamethyl-11-(triethylsilyloxy)-13-[(1,1-dimethylethyl)diphenylsilyloxy]-3-[tris(1-methylethyl)silyloxy]-tridec-3-en-5-one

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Chemical Property of (3EZ,8R,9R,10S,11S,12S)-7-hydroxy-9-(4-methoxyphenylmethoxy)-4,6,8,10,12-pentamethyl-11-(triethylsilyloxy)-13-[(1,1-dimethylethyl)diphenylsilyloxy]-3-[tris(1-methylethyl)silyloxy]-tridec-3-en-5-one

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Technology Process of (3EZ,8R,9R,10S,11S,12S)-7-hydroxy-9-(4-methoxyphenylmethoxy)-4,6,8,10,12-pentamethyl-11-(triethylsilyloxy)-13-[(1,1-dimethylethyl)diphenylsilyloxy]-3-[tris(1-methylethyl)silyloxy]-tridec-3-en-5-one

There total 1 articles about (3EZ,8R,9R,10S,11S,12S)-7-hydroxy-9-(4-methoxyphenylmethoxy)-4,6,8,10,12-pentamethyl-11-(triethylsilyloxy)-13-[(1,1-dimethylethyl)diphenylsilyloxy]-3-[tris(1-methylethyl)silyloxy]-tridec-3-en-5-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 1201668-17-8
C₁₇H₃₄O₂Si

: 1201668-12-3
(2S,3S,4S,5S,6S)-2,4,6-trimethyl-7-[(1,1-dimethylethyl)diphenylsilyloxy]-3-(4-methoxyphenylmethoxy)-5-(triethylsilyloxy)heptanal

: 1201668-18-9
(3EZ,8R,9R,10S,11S,12S)-7-hydroxy-9-(4-methoxyphenylmethoxy)-4,6,8,10,12-pentamethyl-11-(triethylsilyloxy)-13-[(1,1-dimethylethyl)diphenylsilyloxy]-3-[tris(1-methylethyl)silyloxy]-tridec-3-en-5-one

: (3EZ,6R,7S,8R,9R,10S,11S,12S)-7-hydroxy-9-(4-methoxyphenylmethoxy)-4,6,8,10,12-pentamethyl-11-(triethylsilyloxy)-13-[(1,1-dimethylethyl)diphenylsilyloxy]-3-[tris(1-methylethyl)silyloxy]-tridec-3-en-5-one

Guidance literature:: C₁₇H₃₄O₂Si; With lithium diisopropyl amide; In tetrahydrofuran; hexane; at -78 ℃; for 1h; Inert atmosphere;

(2S,3S,4S,5S,6S)-2,4,6-trimethyl-7-[(1,1-dimethylethyl)diphenylsilyloxy]-3-(4-methoxyphenylmethoxy)-5-(triethylsilyloxy)heptanal; In tetrahydrofuran; hexane; at -78 ℃; for 3h; Inert atmosphere;

With methanol; In tetrahydrofuran; hexane; at -78 ℃; Inert atmosphere;
DOI:10.1002/anie.200904607

Reference yield:

: 1201668-18-9
(3EZ,8R,9R,10S,11S,12S)-7-hydroxy-9-(4-methoxyphenylmethoxy)-4,6,8,10,12-pentamethyl-11-(triethylsilyloxy)-13-[(1,1-dimethylethyl)diphenylsilyloxy]-3-[tris(1-methylethyl)silyloxy]-tridec-3-en-5-one

: 1201668-29-2
C₅₇H₉₂O₇Si₃

Guidance literature:: With sodium hydrogencarbonate; Dess-Martin periodane; In dichloromethane; for 1h; Inert atmosphere;
DOI:10.1002/anie.200904607