C₃₄H₅₅IO₇Si

Base Information

Chemical Name:C₃₄H₅₅IO₇Si
CAS No.:1427032-10-7
Molecular Formula:C₃₄H₅₅IO₇Si
Molecular Weight:730.797
Hs Code.:

C<sub>34</sub>H<sub>55</sub>IO<sub>7</sub>Si

Synonyms:C₃₄H₅₅IO₇Si

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Chemical Property of C₃₄H₅₅IO₇Si

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Technology Process of C₃₄H₅₅IO₇Si

There total 27 articles about C₃₄H₅₅IO₇Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 75-47-8
iodoform

: 1427032-08-3
C₃₃H₅₄O₈Si

: 1427032-09-4
C₃₄H₅₅IO₇Si

: 1427032-10-7
C₃₄H₅₅IO₇Si

Guidance literature:: With chromium dichloride; In tetrahydrofuran; 1,4-dioxane; at 20 ℃; for 3h; Overall yield = 81 %; Overall yield = 31.0 mg; diastereoselective reaction;
DOI:10.1002/chem.201600341

Reference yield:

: 1427032-01-6
C₂₀H₂₈O₆

: 1427032-09-4
C₃₄H₅₅IO₇Si

: 1427032-10-7
C₃₄H₅₅IO₇Si

Guidance literature:: Multi-step reaction with 8 steps

1: lithium hydroxide monohydrate / tetrahydrofuran; water; methanol / 0 - 20 °C

2: triethylamine / tetrahydrofuran / 0.83 h / 0 - 20 °C

3: dmap / toluene / 1.5 h / 20 °C

4: Hoveyda-Grubbs catalyst second generation; p-benzoquinone / toluene / 140 °C

5: palladium 10% on activated carbon; hydrogen / methanol / 25 h / 20 °C

6: tetrabutyl ammonium fluoride; acetic acid / tetrahydrofuran / 47 h / 20 °C

7: Dess-Martin periodane / dichloromethane / 0.5 h / 0 - 20 °C

8: chromium dichloride / tetrahydrofuran; 1,4-dioxane / 3 h / 0 - 20 °C

With chromium dichloride; dmap; Hoveyda-Grubbs catalyst second generation; lithium hydroxide monohydrate; palladium 10% on activated carbon; tetrabutyl ammonium fluoride; hydrogen; Dess-Martin periodane; acetic acid; triethylamine; p-benzoquinone; In tetrahydrofuran; 1,4-dioxane; methanol; dichloromethane; water; toluene; 2: |Yamaguchi Lactonization / 8: |Takai-Utimoto Olefination;
DOI:10.1021/ol400408w

Reference yield:

: 1427032-02-7
C₁₉H₂₆O₆

: 1427032-09-4
C₃₄H₅₅IO₇Si

: 1427032-10-7
C₃₄H₅₅IO₇Si

Guidance literature:: Multi-step reaction with 7 steps

1: triethylamine / tetrahydrofuran / 0.83 h / 0 - 20 °C

2: dmap / toluene / 1.5 h / 20 °C

3: Hoveyda-Grubbs catalyst second generation; p-benzoquinone / toluene / 140 °C

4: palladium 10% on activated carbon; hydrogen / methanol / 25 h / 20 °C

5: tetrabutyl ammonium fluoride; acetic acid / tetrahydrofuran / 47 h / 20 °C

6: Dess-Martin periodane / dichloromethane / 0.5 h / 0 - 20 °C

7: chromium dichloride / tetrahydrofuran; 1,4-dioxane / 3 h / 0 - 20 °C

With chromium dichloride; dmap; Hoveyda-Grubbs catalyst second generation; palladium 10% on activated carbon; tetrabutyl ammonium fluoride; hydrogen; Dess-Martin periodane; acetic acid; triethylamine; p-benzoquinone; In tetrahydrofuran; 1,4-dioxane; methanol; dichloromethane; toluene; 1: |Yamaguchi Lactonization / 7: |Takai-Utimoto Olefination;
DOI:10.1021/ol400408w