[(2-(2,6-diisopropyl)anilinoperinaphthenone)Ni(triphenylphosphine)(Ph)]

Base Information

• Chemical Name: [(2-(2,6-diisopropyl)anilinoperinaphthenone)Ni(triphenylphosphine)(Ph)]
• CAS No.: 496789-34-5
• Molecular Formula: C₄₉H₄₄NNiOP
• Molecular Weight: 752.558
• Mol file: 496789-34-5.mol

Synonyms:[(2-(2,6-diisopropyl)anilinoperinaphthenone)Ni(triphenylphosphine)(Ph)]

Chemical Property of [(2-(2,6-diisopropyl)anilinoperinaphthenone)Ni(triphenylphosphine)(Ph)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(2-(2,6-diisopropyl)anilinoperinaphthenone)Ni(triphenylphosphine)(Ph)]

There total 1 articles about [(2-(2,6-diisopropyl)anilinoperinaphthenone)Ni(triphenylphosphine)(Ph)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

bis(triphenylphosphine)nickel phenyl chloride + 2-(2,6-diisopropylanilino)perinaphthenone (496789-32-3) → [(2-(2,6-diisopropyl)anilinoperinaphthenone)Ni(triphenylphosphine)(Ph)] (496789-34-5)

Guidance literature:

With sodium hydride; In tetrahydrofuran; under Ar anilinoperinaphthenone and sodium hydride in THF were stirred for 18 h, (PPh3)2Ni(Ph)(Cl) was added and stirred for 1 h; react. mixt. was filtered, solvent was removed in vacuo, residue was recrystd. from toluene/pentane; elem. anal.;

DOI:10.1021/om020648f

Reference yield:

2-(2,6-diisopropylanilino)perinaphthenone (496789-32-3) + [(2-(2,6-diisopropyl)anilinoperinaphthenone)Ni(triphenylphosphine)(Ph)] (496789-34-5) → [(2-(2,6-diisopropyl)anilinoperinaphthenone)2Ni]

Guidance literature:

In benzene-d6; byproducts: benzene; charging of J-Young tube with (2-(2,6-diisopropyl)anilinoperinaphthenone)Ni(PPh3)Ph (1 equiv.), 2-(2,6-diisopropyl)anilinoperinaphthenone (1 equiv.) and C6D6 at room temp.; heating at 75°C; monitoring by NMR; Kinetics;

DOI:10.1021/ja030634g

upstream raw materials:

2-(2,6-diisopropylanilino)perinaphthenone