6-O-prenyl-2,4-O-bis(tert-butyldimethylsilyl)phloracetophenone

Base Information

• Chemical Name: 6-O-prenyl-2,4-O-bis(tert-butyldimethylsilyl)phloracetophenone
• CAS No.: 1030601-61-6
• Molecular Formula: C₂₅H₄₄O₄Si₂
• Molecular Weight: 464.793
• Mol file: 1030601-61-6.mol

Synonyms:6-O-prenyl-2,4-O-bis(tert-butyldimethylsilyl)phloracetophenone

Chemical Property of 6-O-prenyl-2,4-O-bis(tert-butyldimethylsilyl)phloracetophenone

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of 6-O-prenyl-2,4-O-bis(tert-butyldimethylsilyl)phloracetophenone

There total 1 articles about 6-O-prenyl-2,4-O-bis(tert-butyldimethylsilyl)phloracetophenone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

1-(2,4-bis((tert-butyldimethylsilyl)oxy)-6-hydroxyphenyl)-2-ethan-1-one (108956-90-7) + 3-methyl-2-buten-1-ol (556-82-1) → 6-O-prenyl-2,4-O-bis(tert-butyldimethylsilyl)phloracetophenone (1030601-61-6)

Guidance literature:

With triphenylphosphine; diethylazodicarboxylate; In dichloromethane; at 40 ℃; Inert atmosphere; Cooling with ice;

DOI:10.1021/ol800665w

Reference yield: 81.0%

6-O-prenyl-2,4-O-bis(tert-butyldimethylsilyl)phloracetophenone (1030601-61-6) → 2,4-O-bis(tert-butyldimethylsilyl)-3-prenylphloracetophenone (1030601-54-7)

Guidance literature:

With tris(6,6,7,7,8,8-heptafluoro-2,2-dimethyl-3,5-octadionato)europium(III); In toluene; for 0.5h; Inert atmosphere; Reflux;

DOI:10.1021/ol800665w

upstream raw materials:

1-(2,4-bis((tert-butyldimethylsilyl)oxy)-6-hydroxyphenyl)-2-ethan-1-one

3-methyl-2-buten-1-ol

Downstream raw materials:

2,4-O-bis(tert-butyldimethylsilyl)-3-prenylphloracetophenone