6-(3,5-dibenzyloxyphenoxy)-2,5-bis[(3,5-dibenzyloxyphenoxy)methyl]hexa-1,4-diene

Base Information

Chemical Name:6-(3,5-dibenzyloxyphenoxy)-2,5-bis[(3,5-dibenzyloxyphenoxy)methyl]hexa-1,4-diene
CAS No.:1357487-19-4
Molecular Formula:C₆₈H₆₂O₉
Molecular Weight:1023.23
Hs Code.:

Synonyms:6-(3,5-dibenzyloxyphenoxy)-2,5-bis[(3,5-dibenzyloxyphenoxy)methyl]hexa-1,4-diene

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Chemical Property of 6-(3,5-dibenzyloxyphenoxy)-2,5-bis[(3,5-dibenzyloxyphenoxy)methyl]hexa-1,4-diene

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Technology Process of 6-(3,5-dibenzyloxyphenoxy)-2,5-bis[(3,5-dibenzyloxyphenoxy)methyl]hexa-1,4-diene

There total 6 articles about 6-(3,5-dibenzyloxyphenoxy)-2,5-bis[(3,5-dibenzyloxyphenoxy)methyl]hexa-1,4-diene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 63604-98-8
1,3-dibenzylphloroglucinol

: 1234793-79-3
2-(hydroxymethyl)-5-methylenehex-2-ene-1,6-diol

: 1357487-19-4
6-(3,5-dibenzyloxyphenoxy)-2,5-bis[(3,5-dibenzyloxyphenoxy)methyl]hexa-1,4-diene

Guidance literature:: With triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; toluene; at 0 - 20 ℃;
DOI:10.1016/j.tet.2011.12.062

Reference yield:

: 1071974-82-7
4-(tert-butyldimethylsilyloxy)-3-methylenebutan-1-ol

: 1357487-19-4
6-(3,5-dibenzyloxyphenoxy)-2,5-bis[(3,5-dibenzyloxyphenoxy)methyl]hexa-1,4-diene

Guidance literature:: Multi-step reaction with 5 steps

1.1: 1H-imidazole; iodine; triphenylphosphine / tetrahydrofuran / 0 °C / Inert atmosphere

2.1: acetonitrile / Reflux; Inert atmosphere

3.1: n-butyllithium / 1,2-dimethoxyethane; hexane / 1 h / -78 - -40 °C / Inert atmosphere

3.2: -78 - 0 °C

4.1: water; acetic acid / tetrahydrofuran / 20 °C

5.1: triphenylphosphine; diethylazodicarboxylate / tetrahydrofuran; toluene / 0 - 20 °C

With 1H-imidazole; n-butyllithium; water; iodine; acetic acid; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; 1,2-dimethoxyethane; hexane; toluene; acetonitrile; 5.1: Mitsunobu reaction;
DOI:10.1016/j.tet.2011.12.062

Reference yield:

: 1234793-84-0
2-[(tert-butyldimethylsilyloxy)methyl]-4-iodo-but-1-ene

: 1357487-19-4
6-(3,5-dibenzyloxyphenoxy)-2,5-bis[(3,5-dibenzyloxyphenoxy)methyl]hexa-1,4-diene

Guidance literature:: Multi-step reaction with 4 steps

1.1: acetonitrile / Reflux; Inert atmosphere

2.1: n-butyllithium / 1,2-dimethoxyethane; hexane / 1 h / -78 - -40 °C / Inert atmosphere

2.2: -78 - 0 °C

3.1: water; acetic acid / tetrahydrofuran / 20 °C

4.1: triphenylphosphine; diethylazodicarboxylate / tetrahydrofuran; toluene / 0 - 20 °C

With n-butyllithium; water; acetic acid; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; 1,2-dimethoxyethane; hexane; toluene; acetonitrile; 4.1: Mitsunobu reaction;
DOI:10.1016/j.tet.2011.12.062