Cyclopropanecarboxaldehyde, 2-(phenylmethyl)-, (1S,2S)- (9CI)

Base Information

• Chemical Name: Cyclopropanecarboxaldehyde, 2-(phenylmethyl)-, (1S,2S)- (9CI)
• CAS No.: 397266-15-8
• Molecular Formula: C₁₁H₁₂O
• Molecular Weight: 160.216
• Mol file: 397266-15-8.mol

Synonyms:Cyclopropanecarboxaldehyde, 2-(phenylmethyl)-, (1S,2S)- (9CI)

Chemical Property of Cyclopropanecarboxaldehyde, 2-(phenylmethyl)-, (1S,2S)- (9CI)

Chemical Property:

• PSA: 0.00000
• LogP: 0.00000

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Cyclopropanecarboxaldehyde, 2-(phenylmethyl)-, (1S,2S)- (9CI)

There total 3 articles about Cyclopropanecarboxaldehyde, 2-(phenylmethyl)-, (1S,2S)- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(2-benzylcyclopropyl)methanol (1491138-66-9) → C11H12O (187335-58-6,397266-15-8)

Guidance literature:

(2-benzylcyclopropyl)methanol; With pyridinium chlorochromate; In dichloromethane; at 20 ℃;

With isopropyl alcohol;

DOI:10.1016/j.tet.2013.05.056

Reference yield:

((1S,2S)-2-Benzyl-cyclopropyl)-methanol → (1S,2R)-(+)-2-benzyl-1-formylcyclopropane (187335-58-6,397266-15-8) + (1R,2S)-(-)-2-benzyl-1-formylcyclopropane (187335-58-6,397266-15-8) + (1S,2R)-(-)-2-benzylcyclopropylmethanol + (1R,2S)-(+)-2-benzylcyclopropylmethanol

Guidance literature:

With tert.-butylhydroperoxide; sodium citrate buffer; chloroperoxidase; polyethylenimine; at 20 ℃; for 1h; pH=5.5; Title compound not separated from byproducts.;

DOI:10.1021/jo016161i

Reference yield:

((1S,2S)-2-Benzyl-cyclopropyl)-methanol → (1S,2R)-(+)-2-benzyl-1-formylcyclopropane (187335-58-6,397266-15-8) + (1R,2S)-(-)-2-benzyl-1-formylcyclopropane (187335-58-6,397266-15-8) + (1S,2R)-(-)-2-benzylcyclopropylmethanol + (1R,2S)-(+)-2-benzylcyclopropylmethanol

Guidance literature:

With tert.-butylhydroperoxide; sodium citrate buffer; chloroperoxidase; polyethylenimine; at 20 ℃; for 1h; pH=5.5; Title compound not separated from byproducts.;

DOI:10.1021/jo016161i

upstream raw materials:

(2-benzylcyclopropyl)methanol