Technology Process of 4,4'-( p-BMes2-phenyl)2-2,2'-bpy
There total 1 articles about 4,4'-( p-BMes2-phenyl)2-2,2'-bpy which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
p-bromophenyldimesitylborane;
With
n-butyllithium;
In
tetrahydrofuran;
at -78 ℃;
for 1h;
With
zinc(II) chloride;
In
tetrahydrofuran;
at -78 - 20 ℃;
4,4'-dibromo-2,2'-bipyridine;
With
tetrakis(triphenylphosphine) palladium(0);
In
tetrahydrofuran;
at 55 ℃;
for 48h;
DOI:10.1021/ic1004159
- Guidance literature:
-
In
dichloromethane;
(N2, Schlenk) a soln. of bipyridine-compound and Zn-salt were mixed in CH2Cl2 and stirred for 2 h at room temp.; the solvent was removed, the residue was washed with diethyl ether, dried under vac.;
DOI:10.1021/ic1004159
- Guidance literature:
-
With
(Pt(C6H5)2(μ-SMe2)](n) n=2 or 3;
In
dichloromethane;
(N2, Schlenk) a soln. of Pt-complex and bipyridine-compound in CH2Cl2 was stirred for 12 h under N2 at room temp.; the solvent was removed, the residue was washed with diethyl ether and dried under vac.; elem. anal.;
DOI:10.1021/ic1004159
