(((CH₃)2C₆H₃)2Ge)3

Base Information

• Chemical Name: (((CH₃)2C₆H₃)2Ge)3
• CAS No.: 83269-86-7
• Molecular Formula: C₄₈H₅₄Ge₃
• Molecular Weight: 848.727
• Mol file: 83269-86-7.mol

Synonyms:(((CH₃)2C₆H₃)2Ge)3

Chemical Property of (((CH₃)2C₆H₃)2Ge)3

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of (((CH₃)2C₆H₃)2Ge)3

There total 3 articles about (((CH₃)2C₆H₃)2Ge)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

(2,6-dimethylphenyl)2GeCl2 (83269-89-0) → (((CH3)2C6H3)2Ge)3 (83269-86-7)

Guidance literature:

With magnesium; magnesium bromide; In tetrahydrofuran; to mixt. of Mg, MgBr2 and THF was added a soln. of germane in THF and stirred for 2 h at room temp., mixt. hydrolysed with HCl; mixt. extd. with ether, ext. evapd., hexane added;

DOI:10.1039/c39870001514

Reference yield: 17.0%

(2,6-dimethylphenyl)2GeCl2 (83269-89-0) → (((CH3)2C6H3)2Ge)3 (83269-86-7) + (C6H3(CH3)2)2ClGeGeCl(C6H3(CH3)2)2 + (C6H3(CH3)2)2HGeGeCl(C6H3(CH3)2)2

Guidance literature:

With lithium naphthalenide; In 1,2-dimethoxyethane; byproducts: naphthalene; a soln. of Ge-compound in DME was added a soln. of lithium naphthalenide in DME at -78°C, stirred for 1 h at the same temp., warmed to room temp. for 2 h; flash chromd., recrystd. from cyclohexane;

DOI:10.1021/ja00386a059

Reference yield:

bis(2,6-dimethylphenyl)germanium dihydroxide (83269-90-3) → (((CH3)2C6H3)2Ge)3 (83269-86-7)

Guidance literature:

Multi-step reaction with 2 steps

1: HCl / not given

2: lithium naphthalenide / 1,2-dimethoxyethane

With HCl; lithium naphthalenide; In 1,2-dimethoxyethane;

DOI:10.1021/ja00386a059

upstream raw materials:

(2,6-dimethylphenyl)2GeCl₂

bis(2,6-dimethylphenyl)germanium dihydroxide

Downstream raw materials:

Xy₂Ge=GeXy₂