2-trifluoromethyl-(3,4,6-tri-O-acetyl-1,2-dideoxy-α-D-glucopyranose)-[1,2,d]-2-oxazoline

Base Information

Chemical Name:2-trifluoromethyl-(3,4,6-tri-O-acetyl-1,2-dideoxy-α-D-glucopyranose)-[1,2,d]-2-oxazoline
CAS No.:28719-31-5
Molecular Formula:C₁₄H₁₆F₃NO₈
Molecular Weight:383.278
Hs Code.:

Synonyms:2-trifluoromethyl-(3,4,6-tri-O-acetyl-1,2-dideoxy-α-D-glucopyranose)-[1,2,d]-2-oxazoline

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Chemical Property of 2-trifluoromethyl-(3,4,6-tri-O-acetyl-1,2-dideoxy-α-D-glucopyranose)-[1,2,d]-2-oxazoline

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Technology Process of 2-trifluoromethyl-(3,4,6-tri-O-acetyl-1,2-dideoxy-α-D-glucopyranose)-[1,2,d]-2-oxazoline

There total 2 articles about 2-trifluoromethyl-(3,4,6-tri-O-acetyl-1,2-dideoxy-α-D-glucopyranose)-[1,2,d]-2-oxazoline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 6736-63-6
3,4,6-tri-O-acetyl-2-deoxy-2-trifluoroacetamido-α-D-glucospyranosyl bromide

: 28719-30-4
3,4,6-Tri-O-acetyl-2-trifluoracetamino-2-desoxy-D-glucose

: 28719-31-5
2-trifluoromethyl-(3,4,6-tri-O-acetyl-1,2-dideoxy-α-D-glucopyranose)-[1,2,d]-2-oxazoline

Guidance literature:: With Tetrakis(dimethylamino)ethylen; In tetrahydrofuran; at 20 ℃; for 5h; Reagent/catalyst; Inert atmosphere; UV-irradiation;
DOI:10.1016/j.tet.2013.09.032

Reference yield: 36.0%

: 6736-63-6
3,4,6-tri-O-acetyl-2-deoxy-2-trifluoroacetamido-α-D-glucospyranosyl bromide

: 28719-30-4
3,4,6-Tri-O-acetyl-2-trifluoracetamino-2-desoxy-D-glucose

: C₁₄H₁₈F₃NO₈

: 28719-31-5
2-trifluoromethyl-(3,4,6-tri-O-acetyl-1,2-dideoxy-α-D-glucopyranose)-[1,2,d]-2-oxazoline

Guidance literature:: With Tetrakis(dimethylamino)ethylen; In tetrahydrofuran; for 1.5h; Inert atmosphere; UV-irradiation; Cooling with ice;
DOI:10.1016/j.tet.2013.09.032

Reference yield: 87.7%

: C₁₁₆H₁₂₇F₆N₇O₅₀

: 28719-31-5
2-trifluoromethyl-(3,4,6-tri-O-acetyl-1,2-dideoxy-α-D-glucopyranose)-[1,2,d]-2-oxazoline

: C₁₃₀H₁₄₃F₉N₈O₅₈

Guidance literature:: C₁₁₆H₁₂₇F₆N₇O₅₀; 2-trifluoromethyl-(3,4,6-tri-O-acetyl-1,2-dideoxy-α-D-glucopyranose)-[1,2,d]-2-oxazoline; In dichloromethane; at 20 ℃; for 0.5h; Molecular sieve;

With trifluorormethanesulfonic acid; In dichloromethane; at -40 ℃; for 2.5h; Molecular sieve;
DOI:10.1002/anie.201604190