6-(2,4-Dichlorophenyl)-1-iodo-2,4-O-isopropylidene-D-erythro-2,4-hexanediol

Base Information

Chemical Name:6-(2,4-Dichlorophenyl)-1-iodo-2,4-O-isopropylidene-D-erythro-2,4-hexanediol
CAS No.:141263-61-8
Molecular Formula:C₁₅H₁₉Cl₂IO₂
Molecular Weight:429.125
Hs Code.:

Synonyms:6-(2,4-Dichlorophenyl)-1-iodo-2,4-O-isopropylidene-D-erythro-2,4-hexanediol

Suppliers and Price of 6-(2,4-Dichlorophenyl)-1-iodo-2,4-O-isopropylidene-D-erythro-2,4-hexanediol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 6-(2,4-Dichlorophenyl)-1-iodo-2,4-O-isopropylidene-D-erythro-2,4-hexanediol

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 6-(2,4-Dichlorophenyl)-1-iodo-2,4-O-isopropylidene-D-erythro-2,4-hexanediol

There total 6 articles about 6-(2,4-Dichlorophenyl)-1-iodo-2,4-O-isopropylidene-D-erythro-2,4-hexanediol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.8%

: 141263-59-4
6-(2,4-Dichlorophenyl)-2,4-O-isopropylidene-1-O-p-toluenesulfonyl-D-erythro-1,2,4-hexanetriol

: 141263-61-8
6-(2,4-Dichlorophenyl)-1-iodo-2,4-O-isopropylidene-D-erythro-2,4-hexanediol

Guidance literature:: With sodium iodide; In acetone; for 3h; Heating;
DOI:10.1016/S0008-6215(00)90500-7

Reference yield:

: 101910-02-5,101910-03-6,141263-55-0
(3R,5R)-5-[2-(2,4-Dichloro-phenyl)-ethyl]-tetrahydro-furan-2,3-diol

: 141263-61-8
6-(2,4-Dichlorophenyl)-1-iodo-2,4-O-isopropylidene-D-erythro-2,4-hexanediol

Guidance literature:: Multi-step reaction with 6 steps

1: 95.6 percent / NaBH₄ / ethanol / 1 h / 0 °C

2: 78.8 percent / pyridine / 3 h / Ambient temperature

3: 89.5 percent / p-toluenesulfonic acid, 2-methoxypropene / 0.67 h / 20 °C

4: 95 percent / Bu₄NF / tetrahydrofuran / 0.67 h / 20 °C

5: 81.8 percent / pyridine / 7 h / 20 °C

6: 58.8 percent / NaI / acetone / 3 h / Heating

With pyridine; sodium tetrahydroborate; 2-Methoxypropene; tetrabutyl ammonium fluoride; toluene-4-sulfonic acid; sodium iodide; In tetrahydrofuran; ethanol; acetone;
DOI:10.1016/S0008-6215(00)90500-7

Reference yield:

: 141263-56-1
6-(2,4-Dichlorophenyl)-D-erythro-1,2,4-hexanetriol

: 141263-61-8
6-(2,4-Dichlorophenyl)-1-iodo-2,4-O-isopropylidene-D-erythro-2,4-hexanediol

Guidance literature:: Multi-step reaction with 5 steps

1: 78.8 percent / pyridine / 3 h / Ambient temperature

2: 89.5 percent / p-toluenesulfonic acid, 2-methoxypropene / 0.67 h / 20 °C

3: 95 percent / Bu₄NF / tetrahydrofuran / 0.67 h / 20 °C

4: 81.8 percent / pyridine / 7 h / 20 °C

5: 58.8 percent / NaI / acetone / 3 h / Heating

With pyridine; 2-Methoxypropene; tetrabutyl ammonium fluoride; toluene-4-sulfonic acid; sodium iodide; In tetrahydrofuran; acetone;
DOI:10.1016/S0008-6215(00)90500-7