C₄₉H₆₈O₁₀Si

Base Information

Chemical Name:C₄₉H₆₈O₁₀Si
CAS No.:1264756-80-0
Molecular Formula:C₄₉H₆₈O₁₀Si
Molecular Weight:845.158
Hs Code.:

C<sub>49</sub>H<sub>68</sub>O<sub>10</sub>Si

Synonyms:C₄₉H₆₈O₁₀Si

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Chemical Property of C₄₉H₆₈O₁₀Si

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Technology Process of C₄₉H₆₈O₁₀Si

There total 29 articles about C₄₉H₆₈O₁₀Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 1264756-70-8
C₄₉H₆₆O₁₀Si

: 1264756-80-0
C₄₉H₆₈O₁₀Si

Guidance literature:: With sodium tetrahydroborate; cerium(III) chloride; In methanol; dichloromethane; at 0 ℃;
DOI:10.1016/j.tetlet.2010.11.127

Reference yield:

: 1264756-63-9
C₃₁H₃₈O₆

: 1264756-80-0
C₄₉H₆₈O₁₀Si

Guidance literature:: Multi-step reaction with 13 steps

1.1: sodium hypochlorite; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; sodium hydrogencarbonate; potassium bromide / dichloromethane; water / 0 °C

2.1: sodium hexamethyldisilazane / tetrahydrofuran / 0 °C

3.1: water; 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane / 20 °C

4.1: potassium tert-butylate; tetra-(n-butyl)ammonium iodide / N,N-dimethyl-formamide / 20 °C

5.1: bis-(1,2-dimethylpropyl)borane / tetrahydrofuran / 0 - 20 °C

5.2: 20 °C

6.1: sulfur trioxide pyridine complex; dimethyl sulfoxide; triethylamine / dichloromethane / 20 °C

7.1: diethyl ether / -78 °C

8.1: tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide / dichloromethane / 20 °C / Molecular sieve

9.1: di-n-butylboryl trifluoromethanesulfonate; N-ethyl-N,N-diisopropylamine / diethyl ether / 0 °C

9.2: -78 °C

10.1: Dess-Martin periodane / dichloromethane; tert-butyl alcohol / 20 °C

11.1: pyridinium p-toluenesulfonate / methanol / 80 °C

12.1: 2,6-dimethylpyridine / N,N-dimethyl-formamide / 20 °C

13.1: sodium tetrahydroborate; cerium(III) chloride / methanol; dichloromethane / 0 °C

With 2,6-dimethylpyridine; sodium hypochlorite; sodium tetrahydroborate; cerium(III) chloride; tetrapropylammonium perruthennate; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; di-n-butylboryl trifluoromethanesulfonate; potassium tert-butylate; water; sodium hexamethyldisilazane; sulfur trioxide pyridine complex; pyridinium p-toluenesulfonate; bis-(1,2-dimethylpropyl)borane; tetra-(n-butyl)ammonium iodide; sodium hydrogencarbonate; Dess-Martin periodane; dimethyl sulfoxide; 4-methylmorpholine N-oxide; triethylamine; N-ethyl-N,N-diisopropylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; potassium bromide; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water; N,N-dimethyl-formamide; tert-butyl alcohol; 2.1: Wittig reaction / 7.1: Grignard reaction / 10.1: Dess-Martin oxidation / 13.1: Luche reduction;
DOI:10.1016/j.tetlet.2010.11.127

Reference yield:

: 1264756-60-6
C₃₇H₄₆O₅Si

: 1264756-80-0
C₄₉H₆₈O₁₀Si

Guidance literature:: Multi-step reaction with 18 steps

1.1: potassium tert-butylate / tetrahydrofuran / 20 °C

2.1: water; potassium hydroxide / tetrahydrofuran; methanol

3.1: oxalyl dichloride; dimethyl sulfoxide; triethylamine / dichloromethane / -78 - 20 °C

3.2: 20 °C

4.1: diisobutylaluminium hydride / dichloromethane / -78 °C

5.1: titanium(IV) isopropylate; tert.-butylhydroperoxide; diethyl (2R,3R)-tartrate / dichloromethane / -40 °C / Molecular sieve

6.1: sodium hypochlorite; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; sodium hydrogencarbonate; potassium bromide / dichloromethane; water / 0 °C

7.1: sodium hexamethyldisilazane / tetrahydrofuran / 0 °C

8.1: water; 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane / 20 °C

9.1: potassium tert-butylate; tetra-(n-butyl)ammonium iodide / N,N-dimethyl-formamide / 20 °C

10.1: bis-(1,2-dimethylpropyl)borane / tetrahydrofuran / 0 - 20 °C

10.2: 20 °C

11.1: sulfur trioxide pyridine complex; dimethyl sulfoxide; triethylamine / dichloromethane / 20 °C

12.1: diethyl ether / -78 °C

13.1: tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide / dichloromethane / 20 °C / Molecular sieve

14.1: di-n-butylboryl trifluoromethanesulfonate; N-ethyl-N,N-diisopropylamine / diethyl ether / 0 °C

14.2: -78 °C

15.1: Dess-Martin periodane / dichloromethane; tert-butyl alcohol / 20 °C

16.1: pyridinium p-toluenesulfonate / methanol / 80 °C

17.1: 2,6-dimethylpyridine / N,N-dimethyl-formamide / 20 °C

18.1: sodium tetrahydroborate; cerium(III) chloride / methanol; dichloromethane / 0 °C

With 2,6-dimethylpyridine; titanium(IV) isopropylate; tert.-butylhydroperoxide; sodium hypochlorite; sodium tetrahydroborate; cerium(III) chloride; tetrapropylammonium perruthennate; oxalyl dichloride; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; diethyl (2R,3R)-tartrate; di-n-butylboryl trifluoromethanesulfonate; potassium tert-butylate; water; sodium hexamethyldisilazane; sulfur trioxide pyridine complex; pyridinium p-toluenesulfonate; bis-(1,2-dimethylpropyl)borane; tetra-(n-butyl)ammonium iodide; diisobutylaluminium hydride; sodium hydrogencarbonate; Dess-Martin periodane; dimethyl sulfoxide; 4-methylmorpholine N-oxide; triethylamine; N-ethyl-N,N-diisopropylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; potassium bromide; potassium hydroxide; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water; N,N-dimethyl-formamide; tert-butyl alcohol; 3.1: Swern oxidation / 3.2: Wittig reaction / 5.1: Sharpless asymmetric epoxidation / 7.1: Wittig reaction / 12.1: Grignard reaction / 15.1: Dess-Martin oxidation / 18.1: Luche reduction;
DOI:10.1016/j.tetlet.2010.11.127