(tricyclo<4.2.1.0^2,5>non-7-en-2-yl)triphenylphosphonium perchlorate

Base Information

• Chemical Name: (tricyclo<4.2.1.0^2,5>non-7-en-2-yl)triphenylphosphonium perchlorate
• CAS No.: 101630-41-5
• Molecular Formula: C₂₇H₂₆P*ClO₄
• Molecular Weight: 480.928
• Mol file: 101630-41-5.mol

Synonyms:(tricyclo<4.2.1.0^2,5>non-7-en-2-yl)triphenylphosphonium perchlorate

Chemical Property of (tricyclo<4.2.1.0^2,5>non-7-en-2-yl)triphenylphosphonium perchlorate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (tricyclo<4.2.1.0^2,5>non-7-en-2-yl)triphenylphosphonium perchlorate

There total 1 articles about (tricyclo<4.2.1.0^2,5>non-7-en-2-yl)triphenylphosphonium perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

(1-cyclobutenyl)triphenylphosphonium perchlorate (86046-73-3) + cyclopenta-1,3-diene (542-92-7,25568-84-7,7313-32-8) → (tricyclo<4.2.1.02,5>non-7-en-2-yl)triphenylphosphonium perchlorate (101630-41-5)

Guidance literature:

In dichloromethane; at 140 ℃; for 3h;

DOI:10.1021/jo00362a010

Reference yield: 13.0%

(tricyclo<4.2.1.02,5>non-7-en-2-yl)triphenylphosphonium perchlorate (101630-41-5) → (tricyclo<4.2.1.02,5>non-7-en-2-yl)diphenylphosphine oxide (101630-38-0)

Guidance literature:

With sodium hydroxide; In methanol; for 240h; Heating;

DOI:10.1021/jo00362a010

Reference yield:

(tricyclo<4.2.1.02,5>non-7-en-2-yl)triphenylphosphonium perchlorate (101630-41-5) → (1R,2R,5R,6S)-2-(Diphenyl-phosphinoyl)-tricyclo[4.2.1.02,5]nonane (101630-39-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 13 percent / aq. NaOH / methanol / 240 h / Heating

2: 83 percent / H₂ / PtO₂ / ethanol / 8 h

With sodium hydroxide; hydrogen; platinum(IV) oxide; In methanol; ethanol;

DOI:10.1021/jo00362a010

upstream raw materials:

(1-cyclobutenyl)triphenylphosphonium perchlorate

cyclopenta-1,3-diene

Downstream raw materials:

(tricyclo<4.2.1.0^2,5>non-7-en-2-yl)diphenylphosphine oxide

(1R,2R,5R,6S)-2-(Diphenyl-phosphinoyl)-tricyclo[4.2.1.0^2,5]nonane