5-Acenaphtheneacetic acid

Base Information

• Chemical Name: 5-Acenaphtheneacetic acid
• CAS No.: 10556-23-7
• Molecular Formula: C₁₄H₁₂O₂
• Molecular Weight: 212.248
• NSC Number: 14758
• UNII: DY93UFE74L
• DSSTox Substance ID: DTXSID30147199
• Wikidata: Q83012423
• Mol file: 10556-23-7.mol

Synonyms:5-Acenaphtheneacetic acid;10556-23-7;5-Acenaphthyleneacetic acid, 1,2-dihydro-;2-(1,2-dihydroacenaphthylen-5-yl)acetic acid;DY93UFE74L;NSC-14758;NSC 14758;ChemDiv2_000071;UNII-DY93UFE74L;Oprea1_055834;DTXSID30147199;HMS1369D05;NSC14758;CCG-103822;1,2-DIHYDRO-5-ACENAPHTHYLENEACETIC ACID

Chemical Property of 5-Acenaphtheneacetic acid

Chemical Property:

• Vapor Pressure: 2.06E-08mmHg at 25°C
• Boiling Point: 437.1°Cat760mmHg
• Flash Point: 333.8°C
• Density: 1.307g/cm³
• XLogP3: 2.9
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 212.083729621
• Heavy Atom Count: 16
• Complexity: 287

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CC2=CC=C(C3=CC=CC1=C23)CC(=O)O

Technology Process of 5-Acenaphtheneacetic acid

There total 11 articles about 5-Acenaphtheneacetic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

acenaphthene (83-32-9) + chloroacetic acid (79-11-8) → Acenaphthen-5-yl-essigsaeure (10556-23-7)

Guidance literature:

With iron(III) chloride;

Reference yield:

1a,7b-Dihydro-1H-cyclopropaacenaphthen-1-carbonsaeure → Acenaphthen-5-yl-essigsaeure (10556-23-7)

Guidance literature:

With copper chromite; at 250 - 280 ℃;

DOI:10.1021/ja00969a012

Reference yield:

acenaphthene (83-32-9) → Acenaphthen-5-yl-essigsaeure (10556-23-7)

Guidance literature:

Multi-step reaction with 3 steps

1: AlCl₃

2: aq.-ethanolic NaOH

3: N₂H₄+H₂O / anschliessend Erhitzen mit KOH

With sodium hydroxide; aluminium trichloride; hydrazine hydrate;

upstream raw materials:

5-acetylacenaphthene

acenaphthen-5-yl-glyoxylic acid

acenaphthene

chloroacetic acid