(R)-C3-TunePhos

Base Information

• Chemical Name: (R)-C3-TunePhos
• CAS No.: 301847-89-2
• Molecular Formula: C₃₉H₃₂O₂P₂
• Molecular Weight: 594.629
• European Community (EC) Number: 818-397-1
• Nikkaji Number: J1.470.255E,J2.243.630I
• Mol file: 301847-89-2.mol

Synonyms:(R)-C3-TunePhos;301847-89-2;(R)-C3-TunaPhos;(S)-C3-TunePhos;486429-99-6;(S)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine;MFCD06658115;(R)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine;(17-diphenylphosphanyl-8,12-dioxatricyclo[11.4.0.02,7]heptadeca-1(13),2(7),3,5,14,16-hexaen-3-yl)-diphenylphosphane;SCHEMBL372145;AKOS015951438;R-(-)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin;FT-0701488;D94682;E76416;J-017819;(aR)-2,2'-Bis(diphenylphosphino)-6,6'-(trimethylenebisoxy)biphenyl;1,13-bis(diphenylphosphino)-7,8-dihydro-6h-dibenzo[f,h][1,5]dioxonin;7,8-Dihydro-6H-dibenzo[f,h][1,5]dioxonine-1,13-diylbis(diphenylphosphine);(r)-(-)-1,13-bis(diphenylphosphino)-7,8-dihydro-6h-dibenzo[f,h][1,5]dioxonin;(S)-(+)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin

Chemical Property of (R)-C3-TunePhos

Chemical Property:

• Melting Point: 153-161 °C(lit.)
• Boiling Point: 709.9±60.0 °C(Predicted)
• PSA: 45.64000
• LogP: 7.03130
• Storage Temp.: Inert atmosphere,Room Temperature
• Sensitive.: air sensitive
• XLogP3: 9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 6
• Exact Mass: 594.18775425
• Heavy Atom Count: 43
• Complexity: 710

Purity/Quality:

98%,99%, ^*data from raw suppliers

R-(-)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin, 97% (R)-C3-TUNEPHOS ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1COC2=C(C(=CC=C2)P(C3=CC=CC=C3)C4=CC=CC=C4)C5=C(C=CC=C5P(C6=CC=CC=C6)C7=CC=CC=C7)OC1
• Uses: 1,1''-[(13aR)-7,8-Dihydro-6H-dibenzo[f,h][1,5]dioxonin-1,13-diyl]bis[1,1-diphenylphosphine] is used in the process of preparation of cyclohexyl ethers via ketal hydrogenation. Chiral Quest Phosphine Ligands for Asymmetric HydrogenationLigand used in:Redox-neutral domino reaction of arylethynylbenzylidenearylpentynones catalyzed by gold catalystAsymmetric allylic O-alkylationAsymmetric alkylation of racemic secondary phosphines catalyzed by ruthenium chiral diphosphine hydride complexesStereoselective preparation of cyclopropylcarboxaldehydes via Rh-catalyzed asymmetric hydroformylation of cyclopropenesRhodium-catalyzed asymmetric hydrogenations

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