2-Methyl-3-p-tolylsulfanylmethyl-but-3-en-2-yl-hydroperoxide

Base Information

• Chemical Name: 2-Methyl-3-p-tolylsulfanylmethyl-but-3-en-2-yl-hydroperoxide
• CAS No.: 122145-08-8
• Molecular Formula: C₁₃H₁₈O₂S
• Molecular Weight: 238.351
• Mol file: 122145-08-8.mol

Synonyms:2-Methyl-3-p-tolylsulfanylmethyl-but-3-en-2-yl-hydroperoxide

Chemical Property of 2-Methyl-3-p-tolylsulfanylmethyl-but-3-en-2-yl-hydroperoxide

Chemical Property:

Purity/Quality:

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Technology Process of 2-Methyl-3-p-tolylsulfanylmethyl-but-3-en-2-yl-hydroperoxide

There total 2 articles about 2-Methyl-3-p-tolylsulfanylmethyl-but-3-en-2-yl-hydroperoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,3-Dimethyl-2-butenyl p-methylphenyl sulfide (119561-09-0) → 1-<(4-Methylphenyl)sulfinyl>-2,3-dimethyl-2-butene (51954-48-4) + (S)-2,3-Dimethyl-1-p-tolylsulfanyl-but-3-en-2-yl-hydroperoxide (122145-11-3,123358-95-2) + 2-Methyl-3-p-tolylsulfanylmethyl-but-3-en-2-yl-hydroperoxide (122145-08-8)

Guidance literature:

With oxygen; rose bengal; In acetone; at -78 ℃; Irradiation;

DOI:10.1021/ja00203a023

Reference yield:

2,3-Dimethyl-2-butenyl p-methylphenyl sulfide (119561-09-0) → 1-<(4-Methylphenyl)sulfinyl>-2,3-dimethyl-2-butene (51954-48-4) + 2-Methyl-3-p-tolylsulfanylmethyl-but-3-en-2-yl-hydroperoxide (122145-08-8) + 2-Methyl-3-(toluene-4-sulfinylmethyl)-but-3-en-2-yl-hydroperoxide (114597-50-1) + (R)-2,3-Dimethyl-1-((R)-toluene-4-sulfinyl)-but-3-en-2-yl-hydroperoxide (114597-51-2,122145-13-5,122145-14-6,123358-70-3,123380-79-0) + (R)-2,3-Dimethyl-1-((S)-toluene-4-sulfinyl)-but-3-en-2-yl-hydroperoxide (114597-51-2,122145-13-5,122145-14-6,123358-70-3,123380-79-0) + (S)-2,3-Dimethyl-1-(toluene-4-sulfonyl)-but-3-en-2-yl-hydroperoxide (114597-45-4,122145-15-7)

Guidance literature:

With oxygen; In acetone; at -78 ℃; Product distribution; Irradiation; various temp., diastereoselectivity (10a/10b);

DOI:10.1021/ja00197a044

upstream raw materials:

2,3-Dimethyl-2-butenyl p-methylphenyl sulfide