2,6:8,12-dianhydro-1,3,4,5-tetra-O-benzyl-13-O-tert-butyldiphenylsilyl-10,11-O-isopropylidene-7-O-p-methoxybenzyl-D-lyxo-D-gulo-D-manno-tridecitol

Base Information

Chemical Name:2,6:8,12-dianhydro-1,3,4,5-tetra-O-benzyl-13-O-tert-butyldiphenylsilyl-10,11-O-isopropylidene-7-O-p-methoxybenzyl-D-lyxo-D-gulo-D-manno-tridecitol
CAS No.:931091-49-5
Molecular Formula:C₆₈H₇₈O₁₂Si
Molecular Weight:1115.45
Hs Code.:

2,6:8,12-dianhydro-1,3,4,5-tetra-O-benzyl-13-O-tert-butyldiphenylsilyl-10,11-O-isopropylidene-7-O-p-methoxybenzyl-D-lyxo-D-gulo-D-manno-tridecitol

Synonyms:2,6:8,12-dianhydro-1,3,4,5-tetra-O-benzyl-13-O-tert-butyldiphenylsilyl-10,11-O-isopropylidene-7-O-p-methoxybenzyl-D-lyxo-D-gulo-D-manno-tridecitol

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Chemical Property of 2,6:8,12-dianhydro-1,3,4,5-tetra-O-benzyl-13-O-tert-butyldiphenylsilyl-10,11-O-isopropylidene-7-O-p-methoxybenzyl-D-lyxo-D-gulo-D-manno-tridecitol

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Technology Process of 2,6:8,12-dianhydro-1,3,4,5-tetra-O-benzyl-13-O-tert-butyldiphenylsilyl-10,11-O-isopropylidene-7-O-p-methoxybenzyl-D-lyxo-D-gulo-D-manno-tridecitol

There total 2 articles about 2,6:8,12-dianhydro-1,3,4,5-tetra-O-benzyl-13-O-tert-butyldiphenylsilyl-10,11-O-isopropylidene-7-O-p-methoxybenzyl-D-lyxo-D-gulo-D-manno-tridecitol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 931091-59-7
tert-butyl-{6-[(4-methoxy-benzyloxy)-(3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-methyl]-2,2-dimethyl-3a,7a-dihydro-4H-[1,3]dioxolo[4,5-c]pyran-4-ylmethoxy}-diphenyl-silane

: 931091-49-5
2,6:8,12-dianhydro-1,3,4,5-tetra-O-benzyl-13-O-tert-butyldiphenylsilyl-10,11-O-isopropylidene-7-O-p-methoxybenzyl-D-lyxo-D-gulo-D-manno-tridecitol

Guidance literature:: With dimethylsulfide borane complex; In tetrahydrofuran; at 20 ℃; for 3h;
DOI:10.1002/ejoc.200600825

Reference yield:

: 1053654-89-9
tert-butyl-(2-(2,2-dimethyl-5-phenylsulfanyl-[1,3]dioxolan-4-yl)-2-{1-[(4-methoxy-benzyloxy)-(3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-methyl]-vinyloxy}-ethoxy)-diphenyl-silane

: 931091-49-5
2,6:8,12-dianhydro-1,3,4,5-tetra-O-benzyl-13-O-tert-butyldiphenylsilyl-10,11-O-isopropylidene-7-O-p-methoxybenzyl-D-lyxo-D-gulo-D-manno-tridecitol

Guidance literature:: Multi-step reaction with 2 steps

1: 87 percent / 2,6-di-tert-butylpyridine; 4A MS; methyl triflate / CH₂Cl₂ / 16 h / 20 °C

2: 75 percent / BH₃*Me₂S / tetrahydrofuran / 3 h / 20 °C

With 2,6-di-tert-butyl-pyridine; dimethylsulfide borane complex; methyl trifluoromethanesulfonate; In tetrahydrofuran; dichloromethane;
DOI:10.1002/ejoc.200600825