Technology Process of trans-[Pd(C(N(C6H3Me-2,6))C6H4(C(O)Me)-2)Br(CN(C6H3Me2-2,6))2]
There total 3 articles about trans-[Pd(C(N(C6H3Me-2,6))C6H4(C(O)Me)-2)Br(CN(C6H3Me2-2,6))2] which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
In
dichloromethane;
addn. of Me2C6H3NC (3 equiv.) to soln. of (Pd(2-acetylphenyl)Br(bipy)) (1 equiv.) in CH2Cl2; stirring at room temp. for 2 h; evapn. of solvent, addn. of Et2O, partially evapn., cooling, pptn., filtration, washing with cold Et2O, drying in air;
DOI:10.1021/om020380s
- Guidance literature:
-
In
dichloromethane;
byproducts: PPh3; mixing of Me2C6H3NC (0.05 mmol) and ((Pd(2-cyanophenyl)Br(PPh3)))2 (0.32) in CH2Cl2 under N2; immediately evapn., addn. of Et2O, partially evapn., cooling, pptn., filtration in air, washing with cold Et2O, elem. anal.;
DOI:10.1021/om020380s
- Guidance literature:
-
In
dichloromethane;
byproducts: PPh3; mixing of Me2C6H3NC (3 equiv.) and (Pd(2-acetylphenyl)Br(PPh3)2) (1 equiv.) in CH2Cl2 under N2; immediately evapn., addn. of Et2O, partially evapn., cooling, pptn., filtration in air, washing with cold Et2O;
DOI:10.1021/om020380s
![[Pd(C<sub>6</sub>H<sub>4</sub>(C(O)Me)-2)Br(2,2'-bipyridine)]](/Databaselist/images/loading.webp)
