N'-(9-anthrylmethylene)-N-phenylcarbamohydrazonothioic acid

Base Information

• Chemical Name: N'-(9-anthrylmethylene)-N-phenylcarbamohydrazonothioic acid
• CAS No.: 99007-02-0
• Molecular Formula: C₂₂H₁₇N₃S
• Molecular Weight: 355.463
• Mol file: 99007-02-0.mol

Synonyms:(E)‐1‐((anthracen‐10‐yl)methylene)‐4‐phenylthiosemicarbazide

Chemical Property of N'-(9-anthrylmethylene)-N-phenylcarbamohydrazonothioic acid

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of N'-(9-anthrylmethylene)-N-phenylcarbamohydrazonothioic acid

There total 3 articles about N'-(9-anthrylmethylene)-N-phenylcarbamohydrazonothioic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

4-Phenyl-3-thiosemicarbazide (5351-69-9) + 9-anthracene aldehyde (642-31-9) → (E)‐1‐((anthracen‐10‐yl)methylene)‐4‐phenylthiosemicarbazide (99007-02-0)

Guidance literature:

With acetic acid; In ethanol; at 75 - 80 ℃; for 3h;

DOI:10.1002/bio.3477

Reference yield: 90.0%

anthracen-9-ylmethylene-hydrazone (7512-18-7) + phenyl isothiocyanate (103-72-0) → (E)‐1‐((anthracen‐10‐yl)methylene)‐4‐phenylthiosemicarbazide (99007-02-0)

Guidance literature:

In tetrahydrofuran; at 20 - 80 ℃; for 4.16667h;

DOI:10.1039/d0nj01100b

Reference yield:

9-anthracene aldehyde (642-31-9) → (E)‐1‐((anthracen‐10‐yl)methylene)‐4‐phenylthiosemicarbazide (99007-02-0)

Guidance literature:

Multi-step reaction with 2 steps

1: hydrazine hydrate / methanol / 6 h

2: tetrahydrofuran / 4.17 h / 20 - 80 °C

With hydrazine hydrate; In tetrahydrofuran; methanol;

DOI:10.1039/d0nj01100b

upstream raw materials:

4-Phenyl-3-thiosemicarbazide

9-anthracene aldehyde

anthracen-9-ylmethylene-hydrazone

phenyl isothiocyanate

Downstream raw materials:

[(η6-p-cymene)RuCl(C14H9CHNNHC(S)NH(Ph))]Cl