C₃₁H₄₆O₆S

Base Information

• Chemical Name: C₃₁H₄₆O₆S
• CAS No.: 73697-08-2
• Molecular Formula: C₃₁H₄₆O₆S
• Molecular Weight: 546.769
• Mol file: 73697-08-2.mol

Synonyms:C₃₁H₄₆O₆S

Chemical Property of C₃₁H₄₆O₆S

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₁H₄₆O₆S

There total 11 articles about C₃₁H₄₆O₆S which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C26H40O3S2 (73697-02-6) → C31H46O6S (73697-08-2)

Guidance literature:

Multi-step reaction with 10 steps

1: 97 percent / zinc iodide / CHCl₃ / 40 °C

2: 75 percent / diisobutylaluminium hydride / toluene / 0 °C

3: 80 percent / hexamethylphosphoric acid triamide / -35 °C

4: 80 percent / lithium diisopropylamide / tetrahydrofuran; hexamethylphosphoric acid triamide / 23 °C

5: sodium borohydride / ethanol; tetrahydrofuran / -20 °C

6: 90 percent / 4-dimethylaminopyridine, triethylamine / CHCl₃ / 23 °C

7: 86 percent / 1,3-diiodo-5,5-dimethylhydantoin / acetone; tetrahydrofuran; H₂O / 0.5 h / -20 °C

8: hydrogen / Pd/C / 760 Torr

10: 4-dimethylaminopyridine, triethylamine / CHCl₃ / 23 °C

With dmap; sodium tetrahydroborate; 1,3-Diiodo-5,5-dimethyl-2,4-imidazolidinedione; hydrogen; diisobutylaluminium hydride; triethylamine; zinc(II) iodide; lithium diisopropyl amide; palladium on activated charcoal; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; ethanol; chloroform; water; acetone; toluene;

DOI:10.1021/ja00525a055

Reference yield:

C23H34O4 (73697-01-5) → C31H46O6S (73697-08-2)

Guidance literature:

Multi-step reaction with 11 steps

1: 88 percent / zinc iodide / CHCl₃

2: 97 percent / zinc iodide / CHCl₃ / 40 °C

3: 75 percent / diisobutylaluminium hydride / toluene / 0 °C

4: 80 percent / hexamethylphosphoric acid triamide / -35 °C

5: 80 percent / lithium diisopropylamide / tetrahydrofuran; hexamethylphosphoric acid triamide / 23 °C

6: sodium borohydride / ethanol; tetrahydrofuran / -20 °C

7: 90 percent / 4-dimethylaminopyridine, triethylamine / CHCl₃ / 23 °C

8: 86 percent / 1,3-diiodo-5,5-dimethylhydantoin / acetone; tetrahydrofuran; H₂O / 0.5 h / -20 °C

9: hydrogen / Pd/C / 760 Torr

11: 4-dimethylaminopyridine, triethylamine / CHCl₃ / 23 °C

With dmap; sodium tetrahydroborate; 1,3-Diiodo-5,5-dimethyl-2,4-imidazolidinedione; hydrogen; diisobutylaluminium hydride; triethylamine; zinc(II) iodide; lithium diisopropyl amide; palladium on activated charcoal; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; ethanol; chloroform; water; acetone; toluene;

DOI:10.1021/ja00525a055

Reference yield:

C27H44O3S2 (73697-06-0) → C31H46O6S (73697-08-2)

Guidance literature:

Multi-step reaction with 5 steps

1: 90 percent / 4-dimethylaminopyridine, triethylamine / CHCl₃ / 23 °C

2: 86 percent / 1,3-diiodo-5,5-dimethylhydantoin / acetone; tetrahydrofuran; H₂O / 0.5 h / -20 °C

3: hydrogen / Pd/C / 760 Torr

5: 4-dimethylaminopyridine, triethylamine / CHCl₃ / 23 °C

With dmap; 1,3-Diiodo-5,5-dimethyl-2,4-imidazolidinedione; hydrogen; triethylamine; palladium on activated charcoal; In tetrahydrofuran; chloroform; water; acetone;

DOI:10.1021/ja00525a055

upstream raw materials:

C₂₄H₄₀O₄

p-toluenesulfonyl chloride

C₂₃H₃₄O₄

C₂₆H₄₀O₃S₂

Downstream raw materials:

(+/-)-aphidicolin

C₂₀H₃₄O₄

Refernces