C₄₁H₄₇N₃O₇

Base Information

• Chemical Name: C₄₁H₄₇N₃O₇
• CAS No.: 403704-46-1
• Molecular Formula: C₄₁H₄₇N₃O₇
• Molecular Weight: 693.84
• Mol file: 403704-46-1.mol

Synonyms:C₄₁H₄₇N₃O₇

Chemical Property of C₄₁H₄₇N₃O₇

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₄₁H₄₇N₃O₇

There total 9 articles about C₄₁H₄₇N₃O₇ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C41H47BrO7 (403704-45-0) → C41H47N3O7 (403704-46-1)

Guidance literature:

With TMGN₃; In nitromethane; at 0 - 25 ℃; for 6h;

DOI:10.1021/ol016572l

Reference yield:

Benzoic acid (2S,4aS,4bS,6S,6aR,6bR,7S,8R,9aS,10bR,12aS)-2-acetoxy-4a,6a,7-trimethyl-8-(3-methyl-but-3-enyl)-2,3,4,4a,4b,5,6,6a,6b,7,8,9a,10b,11,12,12a-hexadecahydro-1H-9-oxa-pentaleno[2,1-a]phenanthren-6-yl ester (403704-37-0) → C41H47N3O7 (403704-46-1)

Guidance literature:

Multi-step reaction with 9 steps

1: 96 percent / OsO₄; K₃Fe(CN)6; K₂CO₃ / (DHQ)2PHAL / 2-methyl-propan-2-ol; H₂O / 8 h / 0 °C

2: 97 percent / imidazole; 4-(dimethylamino)pyridine / dimethylformamide / 1.5 h / 25 °C

3: 87 percent / MgBr₂*OEt₂; triethylamine / CH₂Cl₂ / 18 h / 25 °C

4: 96 percent / BF₃*OEt₂ / CH₂Cl₂ / 0.08 h / 0 °C

5: PhI(OAc)2; iodine / cyclohexane; CH₂Cl₂ / 8 h / 0 °C

6: 100 percent / potassium carbonate / methanol; H₂O / 5 h / 25 °C

7: 90 percent / tetrapropylammonium perruthenate; 4-methylmorpholine N-oxide / CH₂Cl₂ / 0.5 h / 25 °C

8: 82 percent / phenyltrimethylammonium tribromide / tetrahydrofuran / 0.25 h / 0 °C

9: TMGN₃ / nitromethane / 6 h / 0 - 25 °C

With 1H-imidazole; dmap; osmium(VIII) oxide; tetrapropylammonium perruthennate; [bis(acetoxy)iodo]benzene; boron trifluoride diethyl etherate; iodine; phenyltrimethylammonium tribromide; potassium carbonate; 4-methylmorpholine N-oxide; triethylamine; magnesium bromide; potassium hexacyanoferrate(III); Hydroquinone 1,4-phthalazinediyl diether; In tetrahydrofuran; methanol; nitromethane; dichloromethane; cyclohexane; water; N,N-dimethyl-formamide; tert-butyl alcohol; 5: Suarez iodine(III) oxidation;

DOI:10.1021/ol016572l

Reference yield:

C41H50O7 (403704-43-8) → C41H47N3O7 (403704-46-1)

Guidance literature:

Multi-step reaction with 3 steps

1: 90 percent / tetrapropylammonium perruthenate; 4-methylmorpholine N-oxide / CH₂Cl₂ / 0.5 h / 25 °C

2: 82 percent / phenyltrimethylammonium tribromide / tetrahydrofuran / 0.25 h / 0 °C

3: TMGN₃ / nitromethane / 6 h / 0 - 25 °C

With tetrapropylammonium perruthennate; phenyltrimethylammonium tribromide; 4-methylmorpholine N-oxide; In tetrahydrofuran; nitromethane; dichloromethane;

DOI:10.1021/ol016572l

upstream raw materials:

C₄₁H₄₇BrO₇

C₄₁H₅₀O₇

Benzoic acid (2S,4aS,4bS,6S,6aR,6bR,7S,8R,9aS,10bR,12aS)-2-acetoxy-4a,6a,7-trimethyl-8-(3-methyl-but-3-enyl)-2,3,4,4a,4b,5,6,6a,6b,7,8,9a,10b,11,12,12a-hexadecahydro-1H-9-oxa-pentaleno[2,1-a]phenanthren-6-yl ester

Benzoic acid (2S,4aS,4bS,6S,6aR,6bR,7S,8R,9aS,10bR,12aS)-2-acetoxy-8-(3,4-dihydroxy-3-methyl-butyl)-4a,6a,7-trimethyl-2,3,4,4a,4b,5,6,6a,6b,7,8,9a,10b,11,12,12a-hexadecahydro-1H-9-oxa-pentaleno[2,1-a]phenanthren-6-yl ester