((2S,3R)-3-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-3-(((tert-butyldiphenylsilyl)oxy)methyl)oxiran-2-yl)methanol

Base Information

Chemical Name:((2S,3R)-3-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-3-(((tert-butyldiphenylsilyl)oxy)methyl)oxiran-2-yl)methanol
CAS No.:744208-84-2
Molecular Formula:C₃₈H₄₈O₄Si₂
Molecular Weight:624.968
Hs Code.:

Synonyms:((2S,3R)-3-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-3-(((tert-butyldiphenylsilyl)oxy)methyl)oxiran-2-yl)methanol

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Chemical Property of ((2S,3R)-3-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-3-(((tert-butyldiphenylsilyl)oxy)methyl)oxiran-2-yl)methanol

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Technology Process of ((2S,3R)-3-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-3-(((tert-butyldiphenylsilyl)oxy)methyl)oxiran-2-yl)methanol

There total 13 articles about ((2S,3R)-3-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-3-(((tert-butyldiphenylsilyl)oxy)methyl)oxiran-2-yl)methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 827036-25-9
C₃₈H₄₈O₃Si₂

: 744208-84-2
((2S,3R)-3-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-3-(((tert-butyldiphenylsilyl)oxy)methyl)oxiran-2-yl)methanol

Guidance literature:: C₃₈H₄₈O₃Si₂; With titanium(IV) isopropylate; diethyl (2R,3R)-tartrate; In dichloromethane; at -20 ℃; for 0.5h;

With tert.-butylhydroperoxide; In dichloromethane; at -25 - -20 ℃; for 2h;

With dimethylsulfide; tartaric acid; more than 3 stages;

Reference yield: 97.0%

: C₃₈H₄₈O₃Si₂

: 744208-84-2
((2S,3R)-3-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-3-(((tert-butyldiphenylsilyl)oxy)methyl)oxiran-2-yl)methanol

Guidance literature:: With titanium(IV) isopropylate; tert.-butylhydroperoxide; diethyl (2R,3R)-tartrate; In dichloromethane; enantioselective reaction;
DOI:10.1016/j.bmcl.2012.10.083

Reference yield: 95.0%

: 1378532-02-5
tert-butyl(((2R,3S)-2-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-3-(((4-methoxybenzyl)oxy)methyl)oxiran-2-yl)methoxy)diphenylsilane

: 744208-84-2
((2S,3R)-3-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-3-(((tert-butyldiphenylsilyl)oxy)methyl)oxiran-2-yl)methanol

Guidance literature:: With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; water; at 20 ℃; for 1.5h; Inert atmosphere;
DOI:10.1002/anie.201200520