(3aS,6S,6aS)-6-methyl-5-[(4-nitrophenyl)sulfonyl]-3,3a,4,5,6,6a-hexahydropyrrolo[3,4-c]pyrazole

Base Information

Chemical Name:(3aS,6S,6aS)-6-methyl-5-[(4-nitrophenyl)sulfonyl]-3,3a,4,5,6,6a-hexahydropyrrolo[3,4-c]pyrazole
CAS No.:1613295-37-6
Molecular Formula:C₁₂H₁₄N₄O₄S
Molecular Weight:310.334
Hs Code.:

Synonyms:(3aS,6S,6aS)-6-methyl-5-[(4-nitrophenyl)sulfonyl]-3,3a,4,5,6,6a-hexahydropyrrolo[3,4-c]pyrazole

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Chemical Property of (3aS,6S,6aS)-6-methyl-5-[(4-nitrophenyl)sulfonyl]-3,3a,4,5,6,6a-hexahydropyrrolo[3,4-c]pyrazole

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Technology Process of (3aS,6S,6aS)-6-methyl-5-[(4-nitrophenyl)sulfonyl]-3,3a,4,5,6,6a-hexahydropyrrolo[3,4-c]pyrazole

There total 5 articles about (3aS,6S,6aS)-6-methyl-5-[(4-nitrophenyl)sulfonyl]-3,3a,4,5,6,6a-hexahydropyrrolo[3,4-c]pyrazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.0%

: 1613295-36-5
(S)-N-allyl-N-[1-(2-tosylhydrazono)propan-2-yl]-4-nitrobenzenesulfonamide

: 1613295-37-6
(3aS,6S,6aS)-6-methyl-5-[(4-nitrophenyl)sulfonyl]-3,3a,4,5,6,6a-hexahydropyrrolo[3,4-c]pyrazole

: 1613295-38-7
(3aS,6S,6aR)-6-methyl-5-[(4-nitrophenyl)sulfonyl]-3,3a,4,5,6,6a-hexahydropyrrolo[3,4-c]pyrazole

: 1613295-39-8
C₁₂H₁₄N₂O₄S

Guidance literature:: With potassium carbonate; In 1,4-dioxane; at 70 ℃; for 7h; Time; stereoselective reaction;
DOI:10.1002/ejoc.201301587

Reference yield:

: 1613295-40-1
(S)-N-allyl-N-(1-hydroxypropan-2-yl)-4-nitro-benzenesulfonamide

: 1613295-37-6
(3aS,6S,6aS)-6-methyl-5-[(4-nitrophenyl)sulfonyl]-3,3a,4,5,6,6a-hexahydropyrrolo[3,4-c]pyrazole

: 1613295-38-7
(3aS,6S,6aR)-6-methyl-5-[(4-nitrophenyl)sulfonyl]-3,3a,4,5,6,6a-hexahydropyrrolo[3,4-c]pyrazole

: 1613295-39-8
C₁₂H₁₄N₂O₄S

Guidance literature:: Multi-step reaction with 3 steps

1: Dess-Martin periodane / dichloromethane / 24 h / 0 °C

2: methanol

3: potassium carbonate / 1,4-dioxane / 7 h / 70 °C

With potassium carbonate; Dess-Martin periodane; In 1,4-dioxane; methanol; dichloromethane; 3: |Bamford-Stevens Decomposition;
DOI:10.1002/ejoc.201301587

Reference yield:

: 1613295-35-4
(S)-N-allyl-N-(1-oxopropan-2-yl)-4-nitro-benzenesulfonamide

: 1613295-37-6
(3aS,6S,6aS)-6-methyl-5-[(4-nitrophenyl)sulfonyl]-3,3a,4,5,6,6a-hexahydropyrrolo[3,4-c]pyrazole

: 1613295-38-7
(3aS,6S,6aR)-6-methyl-5-[(4-nitrophenyl)sulfonyl]-3,3a,4,5,6,6a-hexahydropyrrolo[3,4-c]pyrazole

: 1613295-39-8
C₁₂H₁₄N₂O₄S

Guidance literature:: Multi-step reaction with 2 steps

1: methanol

2: potassium carbonate / 1,4-dioxane / 7 h / 70 °C

With potassium carbonate; In 1,4-dioxane; methanol; 2: |Bamford-Stevens Decomposition;
DOI:10.1002/ejoc.201301587