(3-(2-furyl)-2-sulfanylpropenoato)(triphenylphosphine)gold

Base Information

• Chemical Name: (3-(2-furyl)-2-sulfanylpropenoato)(triphenylphosphine)gold
• CAS No.: 658692-44-5
• Molecular Formula: C₂₅H₂₀AuO₃PS
• Molecular Weight: 628.438
• Mol file: 658692-44-5.mol

Synonyms:(3-(2-furyl)-2-sulfanylpropenoato)(triphenylphosphine)gold

Chemical Property of (3-(2-furyl)-2-sulfanylpropenoato)(triphenylphosphine)gold

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of (3-(2-furyl)-2-sulfanylpropenoato)(triphenylphosphine)gold

There total 1 articles about (3-(2-furyl)-2-sulfanylpropenoato)(triphenylphosphine)gold which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

(triphenylphosphine)gold(I) chloride (14243-64-2) + 3-(2-furyl)-2-sulfanylpropenoic acid (55927-33-8) → (3-(2-furyl)-2-sulfanylpropenoato)(triphenylphosphine)gold (658692-44-5)

Guidance literature:

With KOH; In ethanol; Au(PPh3)Cl added to soln. of sulfanylcarboxylic acid (molar ratio 1:1) and KOH in EtOH, mixt. stirred at room temp. for 1 h; EtOH evapd. under vac., residue washed with H2O, dried under vac.; elem.anal.;

DOI:10.1039/b307192h

Reference yield: 48.0%

(3-(2-furyl)-2-sulfanylpropenoato)(triphenylphosphine)gold (658692-44-5) + diisopropylamine (108-18-9) → diisopropylammonium [Au(PPh3)(3-(2-furyl)-2-sulfanylpropenoato)] (658692-50-3)

Guidance literature:

In ethanol; diisopropylamine added to soln. of Au complex in EtOH (1:1 molar ratio),mixt. stirred at room temp. for 24 h; evapd., solid dried under vac.; elem. anal.;

DOI:10.1039/b307192h

Reference yield:

(triphenylphosphine)gold(I) chloride (14243-64-2) + (3-(2-furyl)-2-sulfanylpropenoato)(triphenylphosphine)gold (658692-44-5) + water (7732-18-5) → [(Au(PPh3))2(3-(2-furyl)-2-sulfanylpropenoato)]*H2O

Guidance literature:

With NaOH; In methanol; Au(PPh3)Cl and NaOH added to soln. of Au complex in MeOH (molar ratio 1:1), mixt. heated under reflux with stirring for 1 h; evapd. under vac., solid washed with H2O, dried under vac.;

DOI:10.1039/b307192h

upstream raw materials:

(triphenylphosphine)gold(I) chloride

3-(2-furyl)-2-sulfanylpropenoic acid

Downstream raw materials:

diisopropylammonium [Au(PPh₃)(3-(2-furyl)-2-sulfanylpropenoato)]

Refernces