zinc(II) 5,15-bis(3,4-dihydroxyphenyl)-10,20-diphenyl-porphyrinate

Base Information

Chemical Name:zinc(II) 5,15-bis(3,4-dihydroxyphenyl)-10,20-diphenyl-porphyrinate
CAS No.:502763-24-8
Molecular Formula:C₄₄H₂₈N₄O₄Zn
Molecular Weight:742.121
Hs Code.:

Synonyms:zinc(II) 5,15-bis(3,4-dihydroxyphenyl)-10,20-diphenyl-porphyrinate

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Chemical Property of zinc(II) 5,15-bis(3,4-dihydroxyphenyl)-10,20-diphenyl-porphyrinate

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Technology Process of zinc(II) 5,15-bis(3,4-dihydroxyphenyl)-10,20-diphenyl-porphyrinate

There total 1 articles about zinc(II) 5,15-bis(3,4-dihydroxyphenyl)-10,20-diphenyl-porphyrinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 5,15-bis(3,4-dihydroxyphenyl)-10,20-diphenyl-21H,23H-porphyrin

: 5970-45-6
zinc(II) acetate dihydrate

: 502763-24-8
zinc(II) 5,15-bis(3,4-dihydroxyphenyl)-10,20-diphenyl-porphyrinate

Guidance literature:: In N,N-dimethyl-formamide; (Ar); ligand dissolved, zinc acetate added, refluxed for 1 h; washed with CHCl3; elem. anal.;
DOI:10.1021/ic048805l

Reference yield: 65.0%

: 17084-13-8
potassium hexafluorophosphate

: bis(2,2'-bipyridine)dichlororuthenium(II) dihydrate

: 502763-24-8
zinc(II) 5,15-bis(3,4-dihydroxyphenyl)-10,20-diphenyl-porphyrinate

: ZnC₂₀H₈N₄(C₆H₅)2(C₆H₃O₂Ru(C₅H₄NC₅H₄N)2)2⁽²⁺⁾*2PF₆^(1-)=[ZnC₂₀H₈N₄(C₆H₅)2(C₆H₃O₂Ru(C₅H₄NC₅H₄N)2)2](PF₆)2

Guidance literature:: With potassium hydroxide; air; In ethanol; to soln. of ligand KOH addedd, warmed to 60 °C under Ar, Ru complex added, refluxed for 5 h in inert atm., cooled to room temp., FcPF6 added, exposed to air with stirring at room temp. for 30 min, aq. KPF6 added; reduced in vac., ppt. filtered off, washed with cold water, diethyl ether, air dried, chromd. (silica, CH3CN/aq. NH4PF6), dried under reduced pressure, redissolved in CH2Cl2, extd. with H2O, org. layer dried, chromd.(Al2O3, CH3CN/toluene);
DOI:10.1021/ic048805l