(2S,3R,4R)-3-benzyloxy-1,2-di-tertbutyldimethylsilyloxy-4-methoxyoctadecane

Base Information

• Chemical Name: (2S,3R,4R)-3-benzyloxy-1,2-di-tertbutyldimethylsilyloxy-4-methoxyoctadecane
• CAS No.: 1242144-36-0
• Molecular Formula: C₃₈H₇₄O₄Si₂
• Molecular Weight: 651.174
• Mol file: 1242144-36-0.mol

Synonyms:(2S,3R,4R)-3-benzyloxy-1,2-di-tertbutyldimethylsilyloxy-4-methoxyoctadecane

Chemical Property of (2S,3R,4R)-3-benzyloxy-1,2-di-tertbutyldimethylsilyloxy-4-methoxyoctadecane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of (2S,3R,4R)-3-benzyloxy-1,2-di-tertbutyldimethylsilyloxy-4-methoxyoctadecane

There total 1 articles about (2S,3R,4R)-3-benzyloxy-1,2-di-tertbutyldimethylsilyloxy-4-methoxyoctadecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

(2S,3R,4R)-3-benzyloxy-1,2-di-tertbutyldimethylsilyloxy-4-methoxyoctadec-5-ene (1353040-49-9) → (2S,3R,4R)-3-benzyloxy-1,2-di-tertbutyldimethylsilyloxy-4-methoxyoctadecane (1242144-36-0)

Guidance literature:

With palladium 10% on activated carbon; hydrogen; In hexane; at 20 ℃; for 0.333333h;

DOI:10.1016/j.carres.2010.05.003

Reference yield: 61.0%

(2S,3R,4R)-3-benzyloxy-1,2-di-tertbutyldimethylsilyloxy-4-methoxyoctadecane (1242144-36-0) → (2S,3S,4R)-3-benzyloxy-4-methoxyoctadecan-1,2-diol (1242144-38-2) + (2S,3R,4R)-3-benzyloxy-2-tert-butyldimethylsilyloxy-4-methoxyoctadecan-1-ol (1242144-37-1)

Guidance literature:

With pyridine; pyridine hydrogenfluoride; In tetrahydrofuran; at 0 - 20 ℃;

DOI:10.1016/j.carres.2010.05.003

upstream raw materials:

(2S,3R,4R)-3-benzyloxy-1,2-di-tertbutyldimethylsilyloxy-4-methoxyoctadec-5-ene

Downstream raw materials:

(2S,3S,4R)-3-benzyloxy-4-methoxyoctadecan-1,2-diol

(2S,3R,4R)-3-benzyloxy-2-tert-butyldimethylsilyloxy-4-methoxyoctadecan-1-ol