3,8-dimethoxy-4,7-bis-(4-isopropyl-2-methylphenyl)benzocinnoline

Base Information

Chemical Name:3,8-dimethoxy-4,7-bis-(4-isopropyl-2-methylphenyl)benzocinnoline
CAS No.:111221-12-6
Molecular Formula:C₃₄H₃₆N₂O₄
Molecular Weight:536.671
Hs Code.:

3,8-dimethoxy-4,7-bis-(4-isopropyl-2-methylphenyl)benzo<c>cinnoline

Synonyms:3,8-dimethoxy-4,7-bis-(4-isopropyl-2-methylphenyl)benzocinnoline

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Chemical Property of 3,8-dimethoxy-4,7-bis-(4-isopropyl-2-methylphenyl)benzocinnoline

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of 3,8-dimethoxy-4,7-bis-(4-isopropyl-2-methylphenyl)benzocinnoline

There total 9 articles about 3,8-dimethoxy-4,7-bis-(4-isopropyl-2-methylphenyl)benzocinnoline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 19177-04-9
1-isopropoxy-3-methylbenzene

: 111221-12-6
3,8-dimethoxy-4,7-bis-(4-isopropyl-2-methylphenyl)benzocinnoline

Guidance literature:: Multi-step reaction with 7 steps

1: 52 g / iodine/periodic acid / acetic acid; H₂O; H₂SO₄ / 6 h

2: 128.6 g / copper(I) t-butoxide / 1,2-dimethoxy-ethane; pyridine / 15 h / 75 - 80 °C

3: 110 g / hexamethylphosphoric acid triamide / 24 h

4: 14.45 g / iodine/periodic acid dihydrate / H₂O; acetic acid; H₂SO₄ / 36 h / 80 °C

5: 6.3 g / copper(II)trifluoromethanesulphonate/copper powder, aq NH₃ / acetone; acetonitrile; dimethylsulfoxide / 1.) 0 deg C, 8 h; 2.) 5 deg C, 12 h

6: 3.6 g / zinc-copper couple / H₂O; acetic acid / 42 h / 125 °C

7: 1.) hydrochloric acid/sodium nitrite, 2.) urea, mercuric iodide/sodium iodide / 1.) dimethylformamide/water, -1 deg C, 3.5 h; 2.) dimethylformamide/water, 0 to 5 deg C, 3 h, dimethylsulfoxide, 120 to 125 deg C, 22 h

With hydrogenchloride; ammonium hydroxide; zinc copper; iodine; copper (I) tert-butoxide; copper(II) bis(trifluoromethanesulfonate); copper; periodic acid; urea; sodium iodide; mercury(II) iodide; sodium nitrite; In pyridine; N,N,N,N,N,N-hexamethylphosphoric triamide; 1,2-dimethoxyethane; sulfuric acid; water; acetic acid; dimethyl sulfoxide; acetone; acetonitrile;

Reference yield:

: 108-39-4
3-methyl-phenol

: 111221-12-6
3,8-dimethoxy-4,7-bis-(4-isopropyl-2-methylphenyl)benzocinnoline

Guidance literature:: Multi-step reaction with 8 steps

1: 70 percent / sodium hydride / dimethylformamide / 5 h / 75 °C

2: 52 g / iodine/periodic acid / acetic acid; H₂O; H₂SO₄ / 6 h

3: 128.6 g / copper(I) t-butoxide / 1,2-dimethoxy-ethane; pyridine / 15 h / 75 - 80 °C

4: 110 g / hexamethylphosphoric acid triamide / 24 h

5: 14.45 g / iodine/periodic acid dihydrate / H₂O; acetic acid; H₂SO₄ / 36 h / 80 °C

6: 6.3 g / copper(II)trifluoromethanesulphonate/copper powder, aq NH₃ / acetone; acetonitrile; dimethylsulfoxide / 1.) 0 deg C, 8 h; 2.) 5 deg C, 12 h

7: 3.6 g / zinc-copper couple / H₂O; acetic acid / 42 h / 125 °C

8: 1.) hydrochloric acid/sodium nitrite, 2.) urea, mercuric iodide/sodium iodide / 1.) dimethylformamide/water, -1 deg C, 3.5 h; 2.) dimethylformamide/water, 0 to 5 deg C, 3 h, dimethylsulfoxide, 120 to 125 deg C, 22 h

With hydrogenchloride; ammonium hydroxide; zinc copper; iodine; copper (I) tert-butoxide; copper(II) bis(trifluoromethanesulfonate); copper; sodium hydride; periodic acid; urea; sodium iodide; mercury(II) iodide; sodium nitrite; In pyridine; N,N,N,N,N,N-hexamethylphosphoric triamide; 1,2-dimethoxyethane; sulfuric acid; water; acetic acid; dimethyl sulfoxide; N,N-dimethyl-formamide; acetone; acetonitrile;

Reference yield:

: 111220-31-6
2-iodo-5-isopropoxytoluene

: 111221-12-6
3,8-dimethoxy-4,7-bis-(4-isopropyl-2-methylphenyl)benzocinnoline

Guidance literature:: Multi-step reaction with 6 steps

1: 128.6 g / copper(I) t-butoxide / 1,2-dimethoxy-ethane; pyridine / 15 h / 75 - 80 °C

2: 110 g / hexamethylphosphoric acid triamide / 24 h

3: 14.45 g / iodine/periodic acid dihydrate / H₂O; acetic acid; H₂SO₄ / 36 h / 80 °C

4: 6.3 g / copper(II)trifluoromethanesulphonate/copper powder, aq NH₃ / acetone; acetonitrile; dimethylsulfoxide / 1.) 0 deg C, 8 h; 2.) 5 deg C, 12 h

5: 3.6 g / zinc-copper couple / H₂O; acetic acid / 42 h / 125 °C

6: 1.) hydrochloric acid/sodium nitrite, 2.) urea, mercuric iodide/sodium iodide / 1.) dimethylformamide/water, -1 deg C, 3.5 h; 2.) dimethylformamide/water, 0 to 5 deg C, 3 h, dimethylsulfoxide, 120 to 125 deg C, 22 h

With hydrogenchloride; ammonium hydroxide; zinc copper; iodine; copper (I) tert-butoxide; copper(II) bis(trifluoromethanesulfonate); copper; periodic acid; urea; sodium iodide; mercury(II) iodide; sodium nitrite; In pyridine; N,N,N,N,N,N-hexamethylphosphoric triamide; 1,2-dimethoxyethane; sulfuric acid; water; acetic acid; dimethyl sulfoxide; acetone; acetonitrile;