BIS(TRIPHENYLPHOSPHORANYLIDENE)-AMMONIUM AZIDE

Base Information

• Chemical Name: BIS(TRIPHENYLPHOSPHORANYLIDENE)-AMMONIUM AZIDE
• CAS No.: 38011-36-8
• Molecular Weight: 580.609
• Hs Code.: 2931900090
• Mol file: 38011-36-8.mol

Synonyms:BIS(TRIPHENYLPHOSPHORANYLIDENE)-AMMONIUM AZIDE

Chemical Property of BIS(TRIPHENYLPHOSPHORANYLIDENE)-AMMONIUM AZIDE

Chemical Property:

• PSA: 91.17000
• LogP: 7.60240

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of BIS(TRIPHENYLPHOSPHORANYLIDENE)-AMMONIUM AZIDE

There total 1 articles about BIS(TRIPHENYLPHOSPHORANYLIDENE)-AMMONIUM AZIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

bis(triphenylphosphine)iminium chloride (21050-13-5) → bis(triphenylphosphorylidene)ammonium azide (38011-36-8)

Guidance literature:

With sodium azide; In water; at 80 ℃; Inert atmosphere;

DOI:10.1002/chem.201406023

Reference yield: 98.0%

{(η5-C5H5)Re(NO)(PPh3)(NH2CH3)}(OSO2CF3) + bis(triphenylphosphorylidene)ammonium azide (38011-36-8) → {(η5-C5H5)Re(NO)(PPh3)(N3)

Guidance literature:

In tetrahydrofuran; byproducts: CH3NH2; stirring for 3 h, under dry N2 atm. solvent removed in vac.; residue extd. with benzene, filtered, addn. of heptane to filtrate, evapn., ppt. filtered, dried in vac. d;

Reference yield: 93.0%

pentafluorophenyl(tetrahydrothiophene)gold(I) + bis(triphenylphosphorylidene)ammonium azide (38011-36-8) → (C6H5)3PNP(C6H5)3(1+)*Au(C6F5)N3(1-)=[(C6H5)3PNP(C6H5)3][Au(C6F5)N3] (74558-99-9)

Guidance literature:

In ethanol; room temp., equimolar amts. (pptn.); filtration, washing (EtOH), further crop on evapn. of filtrate; elem. anal.;

DOI:10.1016/S0020-1693(00)95545-2

upstream raw materials:

bis(triphenylphosphine)iminium chloride

Downstream raw materials:

((C₆H₅)3P)2N⁽¹⁺⁾*{Os₃(NCO)(CO)11}^(1-)=((C₆H₅)3P)2N{Os₃(NCO)(CO)11}

{(PP₃)RhN₃}

{(NP₃)RhN₃}

COFe(P(C₆H₅)3)2(N₂C₆H₄CH₃-p)N₃

Refernces

• 1、 Ni, Kaijie,Kozak, Christopher M.. "Kinetic Studies of Copolymerization of Cyclohexene Oxide with CO2 by a Diamino-bis(phenolate) Chromium(III) Complex". . p. 3097 - 3106. Retrieved 2018.
• 2、 Harloff, J?rg,Schulz, Axel,Stoer, Philip,Villinger, Alexander. "Pseudohalide HCN aggregate ions: [N3(HCN)3]?, [OCN(HCN)3]?, [SCN(HCN)2]?and [P(CN·HCN)2]?". supporting information. p. 13345 - 13351. Retrieved 2020/10/13.