benzyl allyl((R)-2-(benzyloxy)-1-((4R,5R)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl)ethyl)carbamate

Base Information

Chemical Name:benzyl allyl((R)-2-(benzyloxy)-1-((4R,5R)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl)ethyl)carbamate
CAS No.:1384579-00-3
Molecular Formula:C₂₇H₃₃NO₅
Molecular Weight:451.563
Hs Code.:

Synonyms:benzyl allyl((R)-2-(benzyloxy)-1-((4R,5R)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl)ethyl)carbamate

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Chemical Property of benzyl allyl((R)-2-(benzyloxy)-1-((4R,5R)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl)ethyl)carbamate

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Technology Process of benzyl allyl((R)-2-(benzyloxy)-1-((4R,5R)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl)ethyl)carbamate

There total 2 articles about benzyl allyl((R)-2-(benzyloxy)-1-((4R,5R)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl)ethyl)carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 1384578-98-6
benzyl allyl((R)-2-(benzyloxy)-1-((4R,5R)-5-((R)-1,2-dihydroxyethyl)-2,2-dimethyl-1,3-dioxolan-4-yl)ethyl)carbamate

: 1384579-00-3
benzyl allyl((R)-2-(benzyloxy)-1-((4R,5R)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl)ethyl)carbamate

Guidance literature:: With 1H-imidazole; iodine; triphenylphosphine; In toluene; for 3h; Reflux;
DOI:10.1016/j.tetasy.2012.04.017

Reference yield:

: 1384578-97-5
benzyl allyl((R)-2-(benzyloxy)-1-((4S,4'R,5R)-2,2,2',2'-tetramethyl-4,4'-bi(1,3-dioxolan)-5-yl)ethyl)carbamate

: 1384579-00-3
benzyl allyl((R)-2-(benzyloxy)-1-((4R,5R)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl)ethyl)carbamate

Guidance literature:: Multi-step reaction with 2 steps

1.1: water; acetic acid / 16 h / 20 °C

1.2: 0 °C / pH 7

2.1: 1H-imidazole; iodine; triphenylphosphine / toluene / 3 h / Reflux

With 1H-imidazole; water; iodine; acetic acid; triphenylphosphine; In toluene;
DOI:10.1016/j.tetasy.2012.04.017

Reference yield: 91.0%

: 1384579-00-3
benzyl allyl((R)-2-(benzyloxy)-1-((4R,5R)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl)ethyl)carbamate

: 1384579-02-5
(3aR,4R,8aR)-benzyl 4-(benzyloxymethyl)-2,2-dimethyl-6,8a-dihydro-3aH-[1,3]dioxolo[4,5-c]azepine-5(4H)-carboxylate

Guidance literature:: With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In dichloromethane; for 4h; Reflux;
DOI:10.1016/j.tetasy.2012.04.017