1-(Cyclopent-3-en-1-yl)-3-fluorobenzene

Base Information

Chemical Name:1-(Cyclopent-3-en-1-yl)-3-fluorobenzene
CAS No.:369650-25-9
Molecular Formula:C₁₁H₁₁F
Molecular Weight:162.207
Hs Code.:
DSSTox Substance ID:DTXSID00465357
Mol file:369650-25-9.mol

Synonyms:369650-25-9;1-(Cyclopent-3-en-1-yl)-3-fluorobenzene;DTXSID00465357

Suppliers and Price of 1-(Cyclopent-3-en-1-yl)-3-fluorobenzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of 1-(Cyclopent-3-en-1-yl)-3-fluorobenzene

Chemical Property:

PSA：0.00000
LogP:3.25930
XLogP3:3.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:162.084478513
Heavy Atom Count:12
Complexity:166

Purity/Quality:: 99%+ ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1C=CCC1C2=CC(=CC=C2)F

Technology Process of 1-(Cyclopent-3-en-1-yl)-3-fluorobenzene

There total 3 articles about 1-(Cyclopent-3-en-1-yl)-3-fluorobenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1121-86-4
1-Fluoro-3-iodobenzene

: 142-29-0
cyclopentene

: 369650-25-9
1-cyclopent-3-enyl-3-fluoro-benzene

: 369650-08-8
1-cyclopent-2-enyl-3-fluoro-benzene

Guidance literature:: With 4 A molecular sieve; tetrabutyl-ammonium chloride; potassium acetate; palladium diacetate; In N,N-dimethyl-formamide; at 20 ℃; for 36h; Title compound not separated from byproducts;
DOI:10.1016/S0040-4039(01)01045-0

Reference yield:

: C₁₃H₁₅F

: 369650-25-9
1-cyclopent-3-enyl-3-fluoro-benzene

Guidance literature:: With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In dichloromethane;
DOI:10.1016/j.bmcl.2011.08.008

Reference yield:

: 456-48-4
3-Fluorobenzaldehyde

: 369650-25-9
1-cyclopent-3-enyl-3-fluoro-benzene

Guidance literature:: Multi-step reaction with 2 steps

1: titanium tetrachloride / nitromethane / 90 °C

2: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / dichloromethane

With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; titanium tetrachloride; In nitromethane; dichloromethane;
DOI:10.1016/j.bmcl.2011.08.008