6-Oxaspiro[4.5]dec-2-ene-8,9,10-triol, 7-(hydroxymethyl)-, (7R,8S,9S,10S)- (9CI)

Base Information

Chemical Name:6-Oxaspiro[4.5]dec-2-ene-8,9,10-triol, 7-(hydroxymethyl)-, (7R,8S,9S,10S)- (9CI)
CAS No.:369397-30-8
Molecular Formula:C₁₀H₁₆O₅
Molecular Weight:216.234
Hs Code.:
Mol file:369397-30-8.mol

Synonyms:6-Oxaspiro[4.5]dec-2-ene-8,9,10-triol, 7-(hydroxymethyl)-, (7R,8S,9S,10S)- (9CI)

Suppliers and Price of 6-Oxaspiro[4.5]dec-2-ene-8,9,10-triol, 7-(hydroxymethyl)-, (7R,8S,9S,10S)- (9CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 6-Oxaspiro[4.5]dec-2-ene-8,9,10-triol, 7-(hydroxymethyl)-, (7R,8S,9S,10S)- (9CI)

Chemical Property:

PSA：90.15000
LogP:-1.45100

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 6-Oxaspiro[4.5]dec-2-ene-8,9,10-triol, 7-(hydroxymethyl)-, (7R,8S,9S,10S)- (9CI)

There total 5 articles about 6-Oxaspiro[4.5]dec-2-ene-8,9,10-triol, 7-(hydroxymethyl)-, (7R,8S,9S,10S)- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 2,3,4,6-tetra-O-acetylspiro[1,5-anhydro-D-glucitol-1,4'-cyclopent-1'-ene]

: 369397-30-8
spiro[1,5-anhydro-D-glucitol-1,4'-cyclopent-1'-ene]

Guidance literature:: With triethylamine; In methanol; water; at 20 ℃; for 20h;
DOI:10.1002/1099-0690(200108)2001:15<2939::AID-EJOC2939>3.0.CO;2-H

Reference yield:

: 369397-27-3
2,3,4,6-tetra-O-acetylspiro[1,5-anhydro-D-mannitol-1,4'-cyclopent-1'-ene]

: 369397-30-8
spiro[1,5-anhydro-D-mannitol-1,4'-cyclopent-1'-ene]

Guidance literature:: With triethylamine; In methanol; water; at 20 ℃; for 6h;
DOI:10.1002/1099-0690(200108)2001:15<2939::AID-EJOC2939>3.0.CO;2-H

Reference yield:

: 125072-55-1
2,3,4,6-Tetra-O-acetyl-1-chloro-D-mannosyl bromide

: 369397-30-8
spiro[1,5-anhydro-D-mannitol-1,4'-cyclopent-1'-ene]

Guidance literature:: Multi-step reaction with 3 steps

1: 34 percent / AIBN / benzene / 2.5 h / 20 °C / UV-irradiation

2: 89 percent / Grubbs' catalyst / CH₂Cl₂ / 7 h / 20 °C

3: NEt₃ / methanol; H₂O / 6 h / 20 °C

With 2,2'-azobis(isobutyronitrile); triethylamine; Grubbs catalyst first generation; In methanol; dichloromethane; water; benzene;
DOI:10.1002/1099-0690(200108)2001:15<2939::AID-EJOC2939>3.0.CO;2-H