C₄₈H₃₄N₆NiO

Base Information

• Chemical Name: C₄₈H₃₄N₆NiO
• CAS No.: 1415022-00-2
• Molecular Formula: C₄₈H₃₄N₆NiO
• Molecular Weight: 769.528
• Mol file: 1415022-00-2.mol

Synonyms:C₄₈H₃₄N₆NiO

Chemical Property of C₄₈H₃₄N₆NiO

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₄₈H₃₄N₆NiO

There total 3 articles about C₄₈H₃₄N₆NiO which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

benzoimidazole (51-17-2,79351-71-6) + C41H29BrN4NiO (1415021-87-2) → C48H34N6NiO (1415022-00-2)

Guidance literature:

With copper(l) iodide; caesium carbonate; N-benzoyl-N'-phenylhydrazine; In dimethyl sulfoxide; at 120 ℃; Inert atmosphere;

DOI:10.1039/c2cc36800e

Reference yield:

10-(4-methoxyphenyl)-5,15-di-p-tolylporphyrin-nickel (1415021-82-7) → C48H34N6NiO (1415022-00-2)

Guidance literature:

Multi-step reaction with 2 steps

1: N-Bromosuccinimide / dichloromethane; methanol / 0.25 h / 20 °C

2: copper(l) iodide; caesium carbonate; N-benzoyl-N'-phenylhydrazine / dimethyl sulfoxide / 120 °C / Inert atmosphere

With N-Bromosuccinimide; copper(l) iodide; caesium carbonate; N-benzoyl-N'-phenylhydrazine; In methanol; dichloromethane; dimethyl sulfoxide;

DOI:10.1039/c2cc36800e

Reference yield:

C34H24N4Ni (945625-00-3) → C48H34N6NiO (1415022-00-2)

Guidance literature:

Multi-step reaction with 3 steps

1.1: tert.-butyl lithium / tetrahydrofuran; pentane / 2 h / -78 - 20 °C / Inert atmosphere

1.2: 0.33 h / 0 °C

2.1: N-Bromosuccinimide / dichloromethane; methanol / 0.25 h / 20 °C

3.1: copper(l) iodide; caesium carbonate; N-benzoyl-N'-phenylhydrazine / dimethyl sulfoxide / 120 °C / Inert atmosphere

With N-Bromosuccinimide; copper(l) iodide; tert.-butyl lithium; caesium carbonate; N-benzoyl-N'-phenylhydrazine; In tetrahydrofuran; methanol; dichloromethane; dimethyl sulfoxide; pentane;

DOI:10.1039/c2cc36800e

upstream raw materials:

benzoimidazole

C₄₁H₂₉BrN₄NiO

10-(4-methoxyphenyl)-5,15-di-p-tolylporphyrin-nickel

C₃₄H₂₄N₄Ni

Downstream raw materials:

C₅₂H₄₃N₆NiO⁽¹⁺⁾*I^(1-)