4-Methyl-benzenesulfinic acid (R)-[(2E,4E)-deca-2,4-dien-(E)-ylidene]amide

Base Information

Chemical Name:4-Methyl-benzenesulfinic acid (R)-[(2E,4E)-deca-2,4-dien-(E)-ylidene]amide
CAS No.:720682-27-9
Molecular Formula:C₁₇H₂₃NOS
Molecular Weight:289.442
Hs Code.:

Synonyms:4-Methyl-benzenesulfinic acid (R)-[(2E,4E)-deca-2,4-dien-(E)-ylidene]amide

Suppliers and Price of 4-Methyl-benzenesulfinic acid (R)-[(2E,4E)-deca-2,4-dien-(E)-ylidene]amide

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 4-Methyl-benzenesulfinic acid (R)-[(2E,4E)-deca-2,4-dien-(E)-ylidene]amide

Chemical Property:

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Technology Process of 4-Methyl-benzenesulfinic acid (R)-[(2E,4E)-deca-2,4-dien-(E)-ylidene]amide

There total 1 articles about 4-Methyl-benzenesulfinic acid (R)-[(2E,4E)-deca-2,4-dien-(E)-ylidene]amide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 25152-84-5,65909-91-3
trans,trans-2,4-decadienal

: 247089-85-6
(R)-p-toluenesulfinamide

: 720682-27-9
4-Methyl-benzenesulfinic acid (R)-[(2E,4E)-deca-2,4-dien-(E)-ylidene]amide

Guidance literature:: With titanium(IV) tetraethanolate; In dichloromethane; at 20 ℃; for 12h;
DOI:10.1016/j.tet.2004.03.094

Reference yield: 77.0%

: 79-20-9
acetic acid methyl ester

: 720682-27-9
4-Methyl-benzenesulfinic acid (R)-[(2E,4E)-deca-2,4-dien-(E)-ylidene]amide

: 720682-28-0
(R_S,3S)-(-)-methyl 3-[N-(p-toluenesulfinyl)amino]dodeca-4,6-dienoate

Guidance literature:: acetic acid methyl ester; With sodium hexamethyldisilazane; In tetrahydrofuran; diethyl ether; at -78 ℃; for 0.833333h;

4-Methyl-benzenesulfinic acid (R)-[(2E,4E)-deca-2,4-dien-(E)-ylidene]amide; In tetrahydrofuran; diethyl ether; at -78 ℃; for 4h; Further stages.;
DOI:10.1016/j.tet.2004.03.094

Reference yield:

: 720682-27-9
4-Methyl-benzenesulfinic acid (R)-[(2E,4E)-deca-2,4-dien-(E)-ylidene]amide

: 125356-66-3,119463-16-0
(+)-preussin

Guidance literature:: Multi-step reaction with 10 steps

1.1: NaHMDS / diethyl ether; tetrahydrofuran / 0.83 h / -78 °C

1.2: 77 percent / diethyl ether; tetrahydrofuran / 4 h / -78 °C

2.1: NaHMDS / tetrahydrofuran / 1 h / -78 °C

2.2: 78 percent / tetrahydrofuran / 2.83 h / -78 - -15 °C

3.1: CF₃COOH / methanol / 2 h / 20 °C

4.1: 0.130 g / triethylamine; 4-(dimethylamino)pyridine / tetrahydrofuran / 2 h / 0 °C

5.1: 100 percent / H₂ / Pd/C / methanol / 2 h

6.1: 94 percent / p-carboxybenzenesulfonyl azide; triethylamine / acetonitrile / 2 h

7.1: Rh₂(OAc)4 / CH₂Cl₂ / 2 h / 20 °C

8.1: 61 percent / LiAlH₄ / tetrahydrofuran / 78 h / -78 - 70 °C

9.1: I₂; Ph₃P; imidazole / CH₂Cl₂ / 4 h / 0 °C

10.1: CuI / tetrahydrofuran; cyclohexane; diethyl ether / 0.17 h / 0 °C

10.2: 0.016 g / tetrahydrofuran; cyclohexane; diethyl ether / 8 h / 20 °C

With 1H-imidazole; dmap; dirhodium tetraacetate; copper(l) iodide; lithium aluminium tetrahydride; p-carboxybenzenesulfonyl azide; hydrogen; iodine; sodium hexamethyldisilazane; triethylamine; triphenylphosphine; trifluoroacetic acid; palladium on activated charcoal; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; cyclohexane; acetonitrile;
DOI:10.1016/j.tet.2004.03.094