(p-nitrophenyl)azo-tert-cumylmalonitrile

Base Information

• Chemical Name: (p-nitrophenyl)azo-tert-cumylmalonitrile
• CAS No.: 101225-70-1
• Molecular Formula: C₁₈H₁₅N₅O₂
• Molecular Weight: 333.349
• Mol file: 101225-70-1.mol

Synonyms:(p-nitrophenyl)azo-tert-cumylmalonitrile

Chemical Property of (p-nitrophenyl)azo-tert-cumylmalonitrile

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (p-nitrophenyl)azo-tert-cumylmalonitrile

There total 1 articles about (p-nitrophenyl)azo-tert-cumylmalonitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-cyano-3-methyl-3-phenylbutyronitrile (1203-13-0) + 4-nitro-aniline (100-01-6,104810-17-5) → (p-nitrophenyl)azo-tert-cumylmalonitrile (101225-70-1)

Guidance literature:

With hydrogenchloride; sodium acetate; sodium nitrite; Yield given. Multistep reaction; 1.) 0 deg C, H₂O; 2.) water, ethanol, 30 min;

DOI:10.1021/ja00269a042

Reference yield: 95.0%

(p-nitrophenyl)azo-tert-cumylmalonitrile (101225-70-1) → 4-nitrophenylhydrazonopropanedinitrile (3722-12-1) + isopropenylbenzene (98-83-9,6144-04-3,25014-31-7,42612-14-6)

Guidance literature:

In dimethyl sulfoxide; at 60 ℃; Rate constant; decomposition, other solvent, other temperature;

DOI:10.1021/ja00269a042

Reference yield: 94.0%

d(4)-methanol (811-98-3) + (p-nitrophenyl)azo-tert-cumylmalonitrile (101225-70-1) → C10H11(2)H3O (101225-77-8) + isopropenylbenzene (98-83-9,6144-04-3,25014-31-7,42612-14-6)

Guidance literature:

at 60 ℃; Rate constant; decomposition, other solvent;

DOI:10.1021/ja00269a042

upstream raw materials:

2-cyano-3-methyl-3-phenylbutyronitrile

4-nitro-aniline

Downstream raw materials:

4-nitrophenylhydrazonopropanedinitrile

Cumyl methyl ether

isopropenylbenzene

C₁₀H₁₁⁽²⁾H₃O