N-benzyl-N-(5-methyl-4',5'-dipentyl-[2,2']bi[[1,3]dithiolylidene]-4-ylmethyl)-3-(4,5,7-trinitro-9-oxo-9H-fluorene-2-sulfonyl)-propionamide

Base Information

Chemical Name:N-benzyl-N-(5-methyl-4',5'-dipentyl-[2,2']bi[[1,3]dithiolylidene]-4-ylmethyl)-3-(4,5,7-trinitro-9-oxo-9H-fluorene-2-sulfonyl)-propionamide
CAS No.:511552-88-8
Molecular Formula:C₄₁H₄₂N₄O₁₀S₅
Molecular Weight:911.135
Hs Code.:

<i>N</i>-benzyl-<i>N</i>-(5-methyl-4',5'-dipentyl-[2,2']bi[[1,3]dithiolylidene]-4-ylmethyl)-3-(4,5,7-trinitro-9-oxo-9<i>H</i>-fluorene-2-sulfonyl)-propionamide

Synonyms:N-benzyl-N-(5-methyl-4',5'-dipentyl-[2,2']bi[[1,3]dithiolylidene]-4-ylmethyl)-3-(4,5,7-trinitro-9-oxo-9H-fluorene-2-sulfonyl)-propionamide

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Chemical Property of N-benzyl-N-(5-methyl-4',5'-dipentyl-[2,2']bi[[1,3]dithiolylidene]-4-ylmethyl)-3-(4,5,7-trinitro-9-oxo-9H-fluorene-2-sulfonyl)-propionamide

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Technology Process of N-benzyl-N-(5-methyl-4',5'-dipentyl-[2,2']bi[[1,3]dithiolylidene]-4-ylmethyl)-3-(4,5,7-trinitro-9-oxo-9H-fluorene-2-sulfonyl)-propionamide

There total 4 articles about N-benzyl-N-(5-methyl-4',5'-dipentyl-[2,2']bi[[1,3]dithiolylidene]-4-ylmethyl)-3-(4,5,7-trinitro-9-oxo-9H-fluorene-2-sulfonyl)-propionamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

: 347870-38-6
3-(4,5,7-trinitro-9-oxo-2-fluorenylsulfonyl)propanoyl chloride

: 511552-86-6
4-(N-benzylaminomethyl)-5-methyl-4',5'-dipentyltetrathiafulvalene

: 511552-88-8
N-benzyl-N-(5-methyl-4',5'-dipentyl-[2,2']bi[[1,3]dithiolylidene]-4-ylmethyl)-3-(4,5,7-trinitro-9-oxo-9H-fluorene-2-sulfonyl)-propionamide

Guidance literature:: With pyridine; In acetonitrile; at -30 ℃; for 1h;
DOI:10.1002/1521-3765(20021018)8:20<4656::AID-CHEM4656>3.0.CO;2-1

Reference yield:

: 347870-44-4
4-methyl-4',5'-dipentyltetrathiafulvalene

: 511552-88-8
N-benzyl-N-(5-methyl-4',5'-dipentyl-[2,2']bi[[1,3]dithiolylidene]-4-ylmethyl)-3-(4,5,7-trinitro-9-oxo-9H-fluorene-2-sulfonyl)-propionamide

Guidance literature:: Multi-step reaction with 4 steps

1.1: LDA / tetrahydrofuran; heptane; diethyl ether / 2 h / -78 °C

1.2: 66 percent / tetrahydrofuran; heptane; diethyl ether / -78 - 20 °C

2.1: 4 Angstroem molecular sieves / cyclohexane / 15 h / Heating

3.1: 88 mg / LiAlH₄ / diethyl ether / 3.5 h / 20 °C

4.1: 55 percent / pyridine / acetonitrile / 1 h / -30 °C

With pyridine; lithium aluminium tetrahydride; 4 A molecular sieve; lithium diisopropyl amide; In tetrahydrofuran; diethyl ether; n-heptane; cyclohexane; acetonitrile;
DOI:10.1002/1521-3765(20021018)8:20<4656::AID-CHEM4656>3.0.CO;2-1

Reference yield:

: Benzyl-[1-(5-methyl-4',5'-dipentyl-[2,2']bi[[1,3]dithiolylidene]-4-yl)-meth-(E)-ylidene]-amine

: 511552-88-8
N-benzyl-N-(5-methyl-4',5'-dipentyl-[2,2']bi[[1,3]dithiolylidene]-4-ylmethyl)-3-(4,5,7-trinitro-9-oxo-9H-fluorene-2-sulfonyl)-propionamide

Guidance literature:: Multi-step reaction with 2 steps

1: 88 mg / LiAlH₄ / diethyl ether / 3.5 h / 20 °C

2: 55 percent / pyridine / acetonitrile / 1 h / -30 °C

With pyridine; lithium aluminium tetrahydride; In diethyl ether; acetonitrile;
DOI:10.1002/1521-3765(20021018)8:20<4656::AID-CHEM4656>3.0.CO;2-1