(R)-10-(tert-Butyl-diphenyl-silanyloxy)-6-methyl-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinoline

Base Information

Chemical Name:(R)-10-(tert-Butyl-diphenyl-silanyloxy)-6-methyl-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinoline
CAS No.:210830-71-0
Molecular Formula:C₃₃H₃₅NOSi
Molecular Weight:489.733
Hs Code.:

Synonyms:(R)-10-(tert-Butyl-diphenyl-silanyloxy)-6-methyl-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinoline

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Chemical Property of (R)-10-(tert-Butyl-diphenyl-silanyloxy)-6-methyl-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinoline

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Technology Process of (R)-10-(tert-Butyl-diphenyl-silanyloxy)-6-methyl-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinoline

There total 4 articles about (R)-10-(tert-Butyl-diphenyl-silanyloxy)-6-methyl-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinoline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

: 210830-70-9
Trifluoro-methanesulfonic acid (R)-10-(tert-butyl-diphenyl-silanyloxy)-6-methyl-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinolin-11-yl ester

: 210830-71-0
(R)-10-(tert-Butyl-diphenyl-silanyloxy)-6-methyl-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinoline

Guidance literature:: With formic acid; tributyl-amine; 1,3-bis-(diphenylphosphino)propane; bis-triphenylphosphine-palladium(II) chloride; In N,N-dimethyl-formamide; at 80 ℃; for 20h;
DOI:10.1080/00304949809355296

Reference yield:

: 58-00-4
apomorphin

: 210830-71-0
(R)-10-(tert-Butyl-diphenyl-silanyloxy)-6-methyl-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinoline

Guidance literature:: Multi-step reaction with 3 steps

1: 83 percent / imidazole / dimethylformamide / 5 h / Ambient temperature

2: 79 percent / Et₃N, K₂CO₃ / aq. HF / 1.) reflux, 1 h, 2.) reflux, 70 h

3: 56 percent / HCOOH, Ph₂P(CH₂)3PPh₂, Bu₃N / (Ph₃P)2PdCl₂ / dimethylformamide / 20 h / 80 °C

With 1H-imidazole; formic acid; tributyl-amine; 1,3-bis-(diphenylphosphino)propane; potassium carbonate; triethylamine; bis-triphenylphosphine-palladium(II) chloride; In hydrogen fluoride; N,N-dimethyl-formamide;
DOI:10.1080/00304949809355296

Reference yield:

: 58479-61-1
tert-butylchlorodiphenylsilane

: 210830-71-0
(R)-10-(tert-Butyl-diphenyl-silanyloxy)-6-methyl-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinoline

Guidance literature:: Multi-step reaction with 3 steps

1: 83 percent / imidazole / dimethylformamide / 5 h / Ambient temperature

2: 79 percent / Et₃N, K₂CO₃ / aq. HF / 1.) reflux, 1 h, 2.) reflux, 70 h

3: 56 percent / HCOOH, Ph₂P(CH₂)3PPh₂, Bu₃N / (Ph₃P)2PdCl₂ / dimethylformamide / 20 h / 80 °C

With 1H-imidazole; formic acid; tributyl-amine; 1,3-bis-(diphenylphosphino)propane; potassium carbonate; triethylamine; bis-triphenylphosphine-palladium(II) chloride; In hydrogen fluoride; N,N-dimethyl-formamide;
DOI:10.1080/00304949809355296