tert-butyl-(9,9-dimethyl-1,4-dioxa-spiro[4.5]dec-6-en-8-yloxy)-diphenyl-silane

Base Information

Chemical Name:tert-butyl-(9,9-dimethyl-1,4-dioxa-spiro[4.5]dec-6-en-8-yloxy)-diphenyl-silane
CAS No.:851857-08-4
Molecular Formula:C₂₆H₃₄O₃Si
Molecular Weight:422.64
Hs Code.:

<i>tert</i>-butyl-(9,9-dimethyl-1,4-dioxa-spiro[4.5]dec-6-en-8-yloxy)-diphenyl-silane

Synonyms:tert-butyl-(9,9-dimethyl-1,4-dioxa-spiro[4.5]dec-6-en-8-yloxy)-diphenyl-silane

Suppliers and Price of tert-butyl-(9,9-dimethyl-1,4-dioxa-spiro[4.5]dec-6-en-8-yloxy)-diphenyl-silane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of tert-butyl-(9,9-dimethyl-1,4-dioxa-spiro[4.5]dec-6-en-8-yloxy)-diphenyl-silane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of tert-butyl-(9,9-dimethyl-1,4-dioxa-spiro[4.5]dec-6-en-8-yloxy)-diphenyl-silane

There total 3 articles about tert-butyl-(9,9-dimethyl-1,4-dioxa-spiro[4.5]dec-6-en-8-yloxy)-diphenyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 851856-95-6
(R)-9,9-Dimethyl-1,4-dioxa-spiro[4.5]dec-6-en-8-ol

: 92886-86-7
tert-butyldiphenylsilyl triflate

: 851857-08-4
tert-butyl-(9,9-dimethyl-1,4-dioxa-spiro[4.5]dec-6-en-8-yloxy)-diphenyl-silane

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane; at 23 ℃; for 17h;
DOI:10.1021/ja0510616

Reference yield:

: 851857-00-6
9,9-dimethyl-1,4-dioxaspiro[4.5]dec-6-en-8-one

: 851857-08-4
tert-butyl-(9,9-dimethyl-1,4-dioxa-spiro[4.5]dec-6-en-8-yloxy)-diphenyl-silane

Guidance literature:: Multi-step reaction with 2 steps

1: 96 percent / (S)-1-Me-3,3-Ph₂-hexahydropyrrolo[1,2-c][1,3,2]oxaborole; borane*methyl sulfide / tetrahydrofuran; toluene / 26 h / 0 °C

2: 99 percent / 2,6-lutidine / CH₂Cl₂ / 17 h / 23 °C

With 2,6-dimethylpyridine; dimethylsulfide borane complex; (S)-1-Me-3,3-Ph₂-hexahydropyrrolo[1,2-c][1,3,2]oxaborole; In tetrahydrofuran; dichloromethane; toluene;
DOI:10.1021/ja0510616

Reference yield:

: 134409-06-6
4,4-ethylenedioxy-2,2-dimethylcyclohexanone

: 851857-08-4
tert-butyl-(9,9-dimethyl-1,4-dioxa-spiro[4.5]dec-6-en-8-yloxy)-diphenyl-silane

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-butyllithium; hexamethyldisilazane / tetrahydrofuran; hexane / 0.5 h / -78 °C

1.2: TMSCl / tetrahydrofuran; hexane / 0.75 h / -78 - 23 °C

1.3: 98 percent / Pd(OAc)2 / acetonitrile / 48 h / 23 °C

2.1: 96 percent / (S)-1-Me-3,3-Ph₂-hexahydropyrrolo[1,2-c][1,3,2]oxaborole; borane*methyl sulfide / tetrahydrofuran; toluene / 26 h / 0 °C

3.1: 99 percent / 2,6-lutidine / CH₂Cl₂ / 17 h / 23 °C

With 2,6-dimethylpyridine; n-butyllithium; dimethylsulfide borane complex; (S)-1-Me-3,3-Ph₂-hexahydropyrrolo[1,2-c][1,3,2]oxaborole; 1,1,1,3,3,3-hexamethyl-disilazane; In tetrahydrofuran; hexane; dichloromethane; toluene;
DOI:10.1021/ja0510616