{Re2(μ-H)3H2(triphenylphosphine)4(tert-butyl isonitrile)2}PF6

Base Information

Chemical Name:{Re2(μ-H)3H2(triphenylphosphine)4(tert-butyl isonitrile)2}PF6
CAS No.:86676-29-1
Molecular Formula:C₈₂H₈₃N₂P₄Re₂*F₆P
Molecular Weight:1737.85
Hs Code.:

Synonyms:{Re2(μ-H)3H2(triphenylphosphine)4(tert-butyl isonitrile)2}PF6

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Chemical Property of {Re2(μ-H)3H2(triphenylphosphine)4(tert-butyl isonitrile)2}PF6

Chemical Property:

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Technology Process of {Re2(μ-H)3H2(triphenylphosphine)4(tert-butyl isonitrile)2}PF6

There total 3 articles about {Re2(μ-H)3H2(triphenylphosphine)4(tert-butyl isonitrile)2}PF6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: rhenium(PPh3)2H2(μ-H)4(rhenium)H2(PPh3)2

: 119072-55-8,7188-38-7
tert-butylisonitrile

: 86676-29-1
[Re2(μ-H3)H2(P(C6H5)3)4(CN-t-Bu)2]PF6

Guidance literature:: With (C₆H₅)3CPF₆; In dichloromethane; oxidn. of Re2H8(P(C6H5)3)4 with Ph3CPF6; the dark blue soln. maintained at 0°C and stirred for 5 min with tert. butyl isocyanid; filtered, evapd. to dryness, washed with diethyl ether; filtered, evapd. to dryness, washed with diethylether; the crude dark green powder recrystd. from aq. acetone; elem. anal.;

Reference yield:

: 86664-93-9
{Re2(μ-H)4H3(triphenylphosphine)4(tert-butyl isonitrile)}(PF6)2*CH2Cl2

: 119072-55-8,7188-38-7
tert-butylisonitrile

: 80006-29-7
{Re((CH₃)3CNC)4(P(C₆H₅)3)2}⁽¹⁺⁾*PF₆^(1-)={Re((CH₃)3CNC)4(P(C₆H₅)3)2}PF₆

: 86676-29-1
{Re2(μ-H)3H2(triphenylphosphine)4(tert-butyl isonitrile)2}PF6

Guidance literature:: In dichloromethane; byproducts: H2; under N2, 2 h at room temp.; evapn. of solvent under reduced pressure, washed with diethyl ether, dried in vac., not sepd.;
DOI:10.1021/ja00313a033

Reference yield:

: 86676-31-5
{Re2(μ-H)3H2(triphenylphosphine)4(tert-butyl isonitrile)2}(PF6)2

: 119072-55-8,7188-38-7
tert-butylisonitrile

: 80006-29-7
{Re((CH₃)3CNC)4(P(C₆H₅)3)2}⁽¹⁺⁾*PF₆^(1-)={Re((CH₃)3CNC)4(P(C₆H₅)3)2}PF₆

: 86676-29-1
{Re2(μ-H)3H2(triphenylphosphine)4(tert-butyl isonitrile)2}PF6

Guidance literature:: under N2, 2 h at room temp.; evapn. of solvent under reduced pressure, washed with diethyl ether, dried in vac.; product ratio Re2- : Re-compd. = 4:1;
DOI:10.1021/ja00313a033