5-oxa-2,8-dithia[9](2,9)-1,10-phenanthrolinophane

Base Information

• Chemical Name: 5-oxa-2,8-dithia[9](2,9)-1,10-phenanthrolinophane
• CAS No.: 350014-32-3
• Molecular Formula: C₁₈H₁₈N₂OS₂
• Molecular Weight: 342.486
• Mol file: 350014-32-3.mol

Synonyms:5-oxa-2,8-dithia[9](2,9)-1,10-phenanthrolinophane

Chemical Property of 5-oxa-2,8-dithia[9](2,9)-1,10-phenanthrolinophane

Chemical Property:

Purity/Quality:

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Technology Process of 5-oxa-2,8-dithia[9](2,9)-1,10-phenanthrolinophane

There total 1 articles about 5-oxa-2,8-dithia[9](2,9)-1,10-phenanthrolinophane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.7%

2,9-bis-(chloromethyl)-1,10-phenanthroline (87518-61-4) + bis(2-mercaptoethyl)ether (2150-02-9) → 5-oxa-2,8-dithia[9](2,9)-1,10-phenanthrolinophane (350014-32-3)

Guidance literature:

With caesium carbonate; In N,N-dimethyl-formamide; at 55 ℃; for 15h;

DOI:10.1039/b100493j

Reference yield: 47.0%

ammonium hexafluorophosphate + dichlorotetrakis(triphenylphosphine)ruthenium(II) (15555-77-8,86470-43-1) + 5-oxa-2,8-dithia[9](2,9)-1,10-phenanthrolinophane (350014-32-3) → [Ru(5-oxa-2,8-dithia[9](2,9)-1,10-phenanthrolinophane)(PPh3)][PF6]2*0.25(acetonitrile)

Guidance literature:

In methanol; mixt. of ligand and Ru complex in MeOH refluxed under N2 for 2 h, a large excess of NH4PF6 added; solid filtered off, washed (H2O), dried (vac.), recrystd. by slow diffusion of Et2O vapor into a MeCN/MeOH soln.;

DOI:10.1039/b100493j

upstream raw materials:

2,9-bis-(chloromethyl)-1,10-phenanthroline

bis(2-mercaptoethyl)ether