(R)-3-methylcyclohex-2-en-1-yl (S)-6-(tert-butyldiphenylsilyl)oxy-2-diazo-3-oxo-5-(triethylsilyl)oxyhexanoate

Base Information

Chemical Name:(R)-3-methylcyclohex-2-en-1-yl (S)-6-(tert-butyldiphenylsilyl)oxy-2-diazo-3-oxo-5-(triethylsilyl)oxyhexanoate
CAS No.:1582752-84-8
Molecular Formula:C₃₅H₅₀N₂O₅Si₂
Molecular Weight:634.963
Hs Code.:

Synonyms:(R)-3-methylcyclohex-2-en-1-yl (S)-6-(tert-butyldiphenylsilyl)oxy-2-diazo-3-oxo-5-(triethylsilyl)oxyhexanoate

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Chemical Property of (R)-3-methylcyclohex-2-en-1-yl (S)-6-(tert-butyldiphenylsilyl)oxy-2-diazo-3-oxo-5-(triethylsilyl)oxyhexanoate

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Technology Process of (R)-3-methylcyclohex-2-en-1-yl (S)-6-(tert-butyldiphenylsilyl)oxy-2-diazo-3-oxo-5-(triethylsilyl)oxyhexanoate

There total 3 articles about (R)-3-methylcyclohex-2-en-1-yl (S)-6-(tert-butyldiphenylsilyl)oxy-2-diazo-3-oxo-5-(triethylsilyl)oxyhexanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: (R)-3-methylcyclohex-2-en-1-yl (5S)-6-(tert-butyldiphenylsilyl)oxy-2-diazo-5-(triethylsilyl)oxy-3-hydroxyhexanoate

: 1582752-84-8
(R)-3-methylcyclohex-2-en-1-yl (S)-6-(tert-butyldiphenylsilyl)oxy-2-diazo-3-oxo-5-(triethylsilyl)oxyhexanoate

Guidance literature:: With pyridine; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; dimethyl sulfoxide; for 6h; Inert atmosphere;
DOI:10.1021/ol500657f

Reference yield:

: 1582752-73-5
(R)-3-methylcyclohex-2-en-1-yl diazoacetate

: 1582752-84-8
(R)-3-methylcyclohex-2-en-1-yl (S)-6-(tert-butyldiphenylsilyl)oxy-2-diazo-3-oxo-5-(triethylsilyl)oxyhexanoate

Guidance literature:: Multi-step reaction with 2 steps

1: lithium hexamethyldisilazane / tetrahydrofuran; hexane / 0.5 h / -78 °C / Inert atmosphere

2: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; pyridine / tetrahydrofuran; dimethyl sulfoxide / 6 h / Inert atmosphere

With pyridine; lithium hexamethyldisilazane; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; hexane; dimethyl sulfoxide;
DOI:10.1021/ol500657f

Reference yield:

: 905589-27-7
(3S)-4-(tert-butyldiphenylsilyl)oxy-3-(triethylsilyl)oxy-butyraldehyde

: 1582752-84-8
(R)-3-methylcyclohex-2-en-1-yl (S)-6-(tert-butyldiphenylsilyl)oxy-2-diazo-3-oxo-5-(triethylsilyl)oxyhexanoate

Guidance literature:: Multi-step reaction with 2 steps

1: lithium hexamethyldisilazane / tetrahydrofuran; hexane / 0.5 h / -78 °C / Inert atmosphere

2: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; pyridine / tetrahydrofuran; dimethyl sulfoxide / 6 h / Inert atmosphere

With pyridine; lithium hexamethyldisilazane; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; hexane; dimethyl sulfoxide;
DOI:10.1021/ol500657f