Ethyl-2,4-decadienoate

Base Information

• Chemical Name: Ethyl-2,4-decadienoate
• CAS No.: 37549-74-9
• Molecular Formula: C₁₂H₂₀O₂
• Molecular Weight: 196.29
• Hs Code.: 2916199590
• Mol file: 37549-74-9.mol

Synonyms:Ethyl2,4-decadienoate

Chemical Property of Ethyl-2,4-decadienoate

Chemical Property:

• PSA: 26.30000
• LogP: 3.24220

Purity/Quality:

99% ^*data from raw suppliers

ETHYL-2,4-DECADIENOATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Ethyl-2,4-decadienoate

There total 7 articles about Ethyl-2,4-decadienoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.9%

diethoxyphosphoryl-acetic acid ethyl ester (867-13-0) + 2-octen-1-al (2548-87-0,20664-46-4,2363-89-5) → ethyl 2,4-decadienoate (3025-30-7,3025-31-8,7328-34-9,37549-74-9,123474-79-3,136707-82-9)

Guidance literature:

With sodium hydride; In toluene; at 0 ℃; for 0.5h;

DOI:10.1021/jo00363a043

Reference yield:

1,1-diethoxy-oct-2c-ene (16387-56-7) → ethyl 2,4-decadienoate (3025-30-7,3025-31-8,7328-34-9,37549-74-9,123474-79-3,136707-82-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 93.1 percent / p-toluenesulfonic acid / acetone; H₂O / 0.25 h / 0 °C

2: 76.9 percent / sodium hydride / toluene / 0.5 h / 0 °C

With sodium hydride; toluene-4-sulfonic acid; In water; acetone; toluene;

DOI:10.1021/jo00363a043

Reference yield:

1,1-diethoxy-2-octyne (16387-55-6) → ethyl 2,4-decadienoate (3025-30-7,3025-31-8,7328-34-9,37549-74-9,123474-79-3,136707-82-9)

Guidance literature:

Multi-step reaction with 3 steps

1: sodium borohydride, nickel(II) chloride / ethanol; methanol / 3 h / 0 °C

2: 93.1 percent / p-toluenesulfonic acid / acetone; H₂O / 0.25 h / 0 °C

3: 76.9 percent / sodium hydride / toluene / 0.5 h / 0 °C

With sodium tetrahydroborate; sodium hydride; toluene-4-sulfonic acid; nickel dichloride; In methanol; ethanol; water; acetone; toluene;

DOI:10.1021/jo00363a043

upstream raw materials:

4-oxo-but-2-enoic acid ethyl ester

hexylidenetriphenylphosphoran

ethyl 3-(diethylamino)acrylate

(Z)-1-bromo-1-heptene

Downstream raw materials:

(2E,4E)-N-isobutyldecadienamide

(2E,4E)-Deca-2,4-dienoic acid

Refernces